Self-assembly of hybrid solids consisting of 2D supramolecular networks and intercalated metal complexes

Myunghyun Paik Suh; Joong Won Jeon; Hoi Ri Moon; Kil Sik Min; Hye Jin Choi

doi:10.1016/j.crci.2004.10.034

Self-assembly of hybrid solids consisting of 2D supramolecular networks and intercalated metal complexes

Myunghyun Paik Suh, Joong Won Jeon, Hoi Ri Moon, Kil Sik Min, Hye Jin Choi

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Hybrid compounds [NaCr(ox)₃]₂ [Ni(cyclam)][Ni(cyclam)(H₂O)₂]·8 H₂O (1) and [NaCr(ox)₃][Cu(tren)(H₂ O)]·3 H₂O (2) are assembled in MeCN/H₂O from the reaction of Na₃[Cr(ox)₃]·5 H₂O with [Ni(cyclam)](ClO₄)₂ and [Cu(tren)](PF₆)₂, respectively, where cyclam = 1,4,8,11-tetraazacyclotetradecane and tren = tris(2-aminoethyl)amine. In 1 and 2, Ni(II) macrocyclic complex and Cu(II) complex, respectively, are intercalated between the anionic 2D layers of [NaCr(ox)₃] _n^2n-. The magnetic susceptibility data of 1 and 2, measured in the temperature range 5-301K, indicate weak ferromagnetic interactions (θ = 1.9 K for 1 and 0.29 K for 2) between the Cr(III) ions in the 2D layers and the intercalated paramagnetic metal complexes.

Original language	English
Pages (from-to)	1543-1551
Number of pages	9
Journal	Comptes Rendus Chimie
Volume	8
Issue number	9-10 SPEC. ISS.
DOIs	https://doi.org/10.1016/j.crci.2004.10.034
State	Published - Sep 2005

Bibliographical note

Funding Information:
This work was supported by Korea Institute of S&T Evaluation and Planning (Project No. M1-0213-03-0001).

Keywords

2D network
Chromium oxalate
Copper complex
Hybrid compounds
Intercalation
Nickel macrocycle
Self-assembly

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@article{568a9ed2564b46df878ef46672ee541d,

title = "Self-assembly of hybrid solids consisting of 2D supramolecular networks and intercalated metal complexes",

abstract = "Hybrid compounds [NaCr(ox)3]2 [Ni(cyclam)][Ni(cyclam)(H2O)2]·8 H2O (1) and [NaCr(ox)3][Cu(tren)(H2 O)]·3 H2O (2) are assembled in MeCN/H2O from the reaction of Na3[Cr(ox)3]·5 H2O with [Ni(cyclam)](ClO4)2 and [Cu(tren)](PF6)2, respectively, where cyclam = 1,4,8,11-tetraazacyclotetradecane and tren = tris(2-aminoethyl)amine. In 1 and 2, Ni(II) macrocyclic complex and Cu(II) complex, respectively, are intercalated between the anionic 2D layers of [NaCr(ox)3] n2n-. The magnetic susceptibility data of 1 and 2, measured in the temperature range 5-301K, indicate weak ferromagnetic interactions (θ = 1.9 K for 1 and 0.29 K for 2) between the Cr(III) ions in the 2D layers and the intercalated paramagnetic metal complexes.",

keywords = "2D network, Chromium oxalate, Copper complex, Hybrid compounds, Intercalation, Nickel macrocycle, Self-assembly",

author = "Suh, {Myunghyun Paik} and Jeon, {Joong Won} and Moon, {Hoi Ri} and Min, {Kil Sik} and Choi, {Hye Jin}",

note = "Funding Information: This work was supported by Korea Institute of S&T Evaluation and Planning (Project No. M1-0213-03-0001).",

year = "2005",

month = sep,

doi = "10.1016/j.crci.2004.10.034",

language = "English",

volume = "8",

pages = "1543--1551",

journal = "Comptes Rendus Chimie",

issn = "1631-0748",

publisher = "Academie des sciences",

number = "9-10 SPEC. ISS.",

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T1 - Self-assembly of hybrid solids consisting of 2D supramolecular networks and intercalated metal complexes

AU - Suh, Myunghyun Paik

AU - Jeon, Joong Won

AU - Moon, Hoi Ri

AU - Min, Kil Sik

AU - Choi, Hye Jin

N1 - Funding Information: This work was supported by Korea Institute of S&T Evaluation and Planning (Project No. M1-0213-03-0001).

PY - 2005/9

Y1 - 2005/9

N2 - Hybrid compounds [NaCr(ox)3]2 [Ni(cyclam)][Ni(cyclam)(H2O)2]·8 H2O (1) and [NaCr(ox)3][Cu(tren)(H2 O)]·3 H2O (2) are assembled in MeCN/H2O from the reaction of Na3[Cr(ox)3]·5 H2O with [Ni(cyclam)](ClO4)2 and [Cu(tren)](PF6)2, respectively, where cyclam = 1,4,8,11-tetraazacyclotetradecane and tren = tris(2-aminoethyl)amine. In 1 and 2, Ni(II) macrocyclic complex and Cu(II) complex, respectively, are intercalated between the anionic 2D layers of [NaCr(ox)3] n2n-. The magnetic susceptibility data of 1 and 2, measured in the temperature range 5-301K, indicate weak ferromagnetic interactions (θ = 1.9 K for 1 and 0.29 K for 2) between the Cr(III) ions in the 2D layers and the intercalated paramagnetic metal complexes.

AB - Hybrid compounds [NaCr(ox)3]2 [Ni(cyclam)][Ni(cyclam)(H2O)2]·8 H2O (1) and [NaCr(ox)3][Cu(tren)(H2 O)]·3 H2O (2) are assembled in MeCN/H2O from the reaction of Na3[Cr(ox)3]·5 H2O with [Ni(cyclam)](ClO4)2 and [Cu(tren)](PF6)2, respectively, where cyclam = 1,4,8,11-tetraazacyclotetradecane and tren = tris(2-aminoethyl)amine. In 1 and 2, Ni(II) macrocyclic complex and Cu(II) complex, respectively, are intercalated between the anionic 2D layers of [NaCr(ox)3] n2n-. The magnetic susceptibility data of 1 and 2, measured in the temperature range 5-301K, indicate weak ferromagnetic interactions (θ = 1.9 K for 1 and 0.29 K for 2) between the Cr(III) ions in the 2D layers and the intercalated paramagnetic metal complexes.

KW - 2D network

KW - Chromium oxalate

KW - Copper complex

KW - Hybrid compounds

KW - Intercalation

KW - Nickel macrocycle

KW - Self-assembly

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U2 - 10.1016/j.crci.2004.10.034

DO - 10.1016/j.crci.2004.10.034

M3 - Article

AN - SCOPUS:26944470725

SN - 1631-0748

VL - 8

SP - 1543

EP - 1551

JO - Comptes Rendus Chimie

JF - Comptes Rendus Chimie

IS - 9-10 SPEC. ISS.

ER -

Self-assembly of hybrid solids consisting of 2D supramolecular networks and intercalated metal complexes

Abstract

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Keywords

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