Selective synthesis of [12]cyeloparaphenylene

Hiroko Takaba; Haruka Omachi; Yosuke Yamamoto; Jean Bouffard; Kenichiro Itami

doi:10.1002/anie.200902617

Selective synthesis of [12]cyeloparaphenylene

Hiroko Takaba, Haruka Omachi, Yosuke Yamamoto, Jean Bouffard, Kenichiro Itami

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

442 Scopus citations

Abstract

Tighten your belt: [12]Cycloparaphenylene, the sidewall segment of a carbon nanotube (see picture), has been synthesized in a selective manner through stepwise palladium-catalyzed coupling reactions. The synthesis capitalizes on the ability of the cis-1,4-dihydroxycyclohexane- 1,4-diyl unit to attenuate the build-up of strain energy during macrocyclization.

Original language	English
Pages (from-to)	6112-6116
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	48
Issue number	33
DOIs	https://doi.org/10.1002/anie.200902617
State	Published - 2009

Keywords

Aromaticity
Cross-coupling
Cycloparaphenylenes
Macrocyclization
Palladium

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title = "Selective synthesis of [12]cyeloparaphenylene",

abstract = "Tighten your belt: [12]Cycloparaphenylene, the sidewall segment of a carbon nanotube (see picture), has been synthesized in a selective manner through stepwise palladium-catalyzed coupling reactions. The synthesis capitalizes on the ability of the cis-1,4-dihydroxycyclohexane- 1,4-diyl unit to attenuate the build-up of strain energy during macrocyclization.",

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AU - Takaba, Hiroko

AU - Omachi, Haruka

AU - Yamamoto, Yosuke

AU - Bouffard, Jean

AU - Itami, Kenichiro

PY - 2009

Y1 - 2009

N2 - Tighten your belt: [12]Cycloparaphenylene, the sidewall segment of a carbon nanotube (see picture), has been synthesized in a selective manner through stepwise palladium-catalyzed coupling reactions. The synthesis capitalizes on the ability of the cis-1,4-dihydroxycyclohexane- 1,4-diyl unit to attenuate the build-up of strain energy during macrocyclization.

AB - Tighten your belt: [12]Cycloparaphenylene, the sidewall segment of a carbon nanotube (see picture), has been synthesized in a selective manner through stepwise palladium-catalyzed coupling reactions. The synthesis capitalizes on the ability of the cis-1,4-dihydroxycyclohexane- 1,4-diyl unit to attenuate the build-up of strain energy during macrocyclization.

KW - Aromaticity

KW - Cross-coupling

KW - Cycloparaphenylenes

KW - Macrocyclization

KW - Palladium

UR - https://www.scopus.com/pages/publications/70349902686

U2 - 10.1002/anie.200902617

DO - 10.1002/anie.200902617

M3 - Article

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AN - SCOPUS:70349902686

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 33

ER -

Selective synthesis of [12]cyeloparaphenylene

Abstract

Keywords

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