Selective synthesis of [12]cyeloparaphenylene

Hiroko Takaba; Haruka Omachi; Yosuke Yamamoto; Jean Bouffard; Kenichiro Itami

doi:10.1002/anie.200902617

Selective synthesis of [12]cyeloparaphenylene

Hiroko Takaba, Haruka Omachi, Yosuke Yamamoto, Jean Bouffard, Kenichiro Itami

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

401 Scopus citations

Abstract

Tighten your belt: [12]Cycloparaphenylene, the sidewall segment of a carbon nanotube (see picture), has been synthesized in a selective manner through stepwise palladium-catalyzed coupling reactions. The synthesis capitalizes on the ability of the cis-1,4-dihydroxycyclohexane- 1,4-diyl unit to attenuate the build-up of strain energy during macrocyclization.

Original language	English
Pages (from-to)	6112-6116
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	48
Issue number	33
DOIs	https://doi.org/10.1002/anie.200902617
State	Published - 2009

Keywords

Aromaticity
Cross-coupling
Cycloparaphenylenes
Macrocyclization
Palladium

Access to Document

10.1002/anie.200902617

Cite this

@article{8b93d140bea94efbaac7511aafc893f5,

title = "Selective synthesis of [12]cyeloparaphenylene",

abstract = "Tighten your belt: [12]Cycloparaphenylene, the sidewall segment of a carbon nanotube (see picture), has been synthesized in a selective manner through stepwise palladium-catalyzed coupling reactions. The synthesis capitalizes on the ability of the cis-1,4-dihydroxycyclohexane- 1,4-diyl unit to attenuate the build-up of strain energy during macrocyclization.",

keywords = "Aromaticity, Cross-coupling, Cycloparaphenylenes, Macrocyclization, Palladium",

author = "Hiroko Takaba and Haruka Omachi and Yosuke Yamamoto and Jean Bouffard and Kenichiro Itami",

year = "2009",

doi = "10.1002/anie.200902617",

language = "English",

volume = "48",

pages = "6112--6116",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "33",

}

TY - JOUR

T1 - Selective synthesis of [12]cyeloparaphenylene

AU - Takaba, Hiroko

AU - Omachi, Haruka

AU - Yamamoto, Yosuke

AU - Bouffard, Jean

AU - Itami, Kenichiro

PY - 2009

Y1 - 2009

N2 - Tighten your belt: [12]Cycloparaphenylene, the sidewall segment of a carbon nanotube (see picture), has been synthesized in a selective manner through stepwise palladium-catalyzed coupling reactions. The synthesis capitalizes on the ability of the cis-1,4-dihydroxycyclohexane- 1,4-diyl unit to attenuate the build-up of strain energy during macrocyclization.

AB - Tighten your belt: [12]Cycloparaphenylene, the sidewall segment of a carbon nanotube (see picture), has been synthesized in a selective manner through stepwise palladium-catalyzed coupling reactions. The synthesis capitalizes on the ability of the cis-1,4-dihydroxycyclohexane- 1,4-diyl unit to attenuate the build-up of strain energy during macrocyclization.

KW - Aromaticity

KW - Cross-coupling

KW - Cycloparaphenylenes

KW - Macrocyclization

KW - Palladium

UR - http://www.scopus.com/inward/record.url?scp=70349902686&partnerID=8YFLogxK

U2 - 10.1002/anie.200902617

DO - 10.1002/anie.200902617

M3 - Article

C2 - 19588479

AN - SCOPUS:70349902686

SN - 1433-7851

VL - 48

SP - 6112

EP - 6116

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 33

ER -

Selective synthesis of [12]cyeloparaphenylene

Abstract

Keywords

Access to Document

Fingerprint

Cite this