Scandium ion-accelerated scavenging reaction of cumylperoxyl radical by a cyclic nitroxyl radical via electron transfer

Ikuo Nakanishi; Kumiko Kawaguchi; Kei Ohkubo; Tomonori Kawashima; Sushma Manda; Hideko Kanazawa; Keizo Takeshita; Kazunori Anzai; Toshihiko Ozawa; Shunichi Fukuzumi; Nobuo Ikota

doi:10.1246/cl.2007.378

Scandium ion-accelerated scavenging reaction of cumylperoxyl radical by a cyclic nitroxyl radical via electron transfer

Ikuo Nakanishi, Kumiko Kawaguchi, Kei Ohkubo, Tomonori Kawashima, Sushma Manda, Hideko Kanazawa, Keizo Takeshita, Kazunori Anzai, Toshihiko Ozawa, Shunichi Fukuzumi, Nobuo Ikota

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

A cyclic nitroxyl radical used as a spin probe efficiently scavenges cumylperoxyl radical in an aprotic medium via an electron-transfer process, which is significantly accelerated by the presence of scandium ion.

Original language	English
Pages (from-to)	378-379
Number of pages	2
Journal	Chemistry Letters
Volume	36
Issue number	3
DOIs	https://doi.org/10.1246/cl.2007.378
State	Published - 5 Mar 2007

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title = "Scandium ion-accelerated scavenging reaction of cumylperoxyl radical by a cyclic nitroxyl radical via electron transfer",

abstract = "A cyclic nitroxyl radical used as a spin probe efficiently scavenges cumylperoxyl radical in an aprotic medium via an electron-transfer process, which is significantly accelerated by the presence of scandium ion.",

author = "Ikuo Nakanishi and Kumiko Kawaguchi and Kei Ohkubo and Tomonori Kawashima and Sushma Manda and Hideko Kanazawa and Keizo Takeshita and Kazunori Anzai and Toshihiko Ozawa and Shunichi Fukuzumi and Nobuo Ikota",

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language = "English",

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journal = "Chemistry Letters",

issn = "0366-7022",

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T1 - Scandium ion-accelerated scavenging reaction of cumylperoxyl radical by a cyclic nitroxyl radical via electron transfer

AU - Nakanishi, Ikuo

AU - Kawaguchi, Kumiko

AU - Ohkubo, Kei

AU - Kawashima, Tomonori

AU - Manda, Sushma

AU - Kanazawa, Hideko

AU - Takeshita, Keizo

AU - Anzai, Kazunori

AU - Ozawa, Toshihiko

AU - Fukuzumi, Shunichi

AU - Ikota, Nobuo

PY - 2007/3/5

Y1 - 2007/3/5

N2 - A cyclic nitroxyl radical used as a spin probe efficiently scavenges cumylperoxyl radical in an aprotic medium via an electron-transfer process, which is significantly accelerated by the presence of scandium ion.

AB - A cyclic nitroxyl radical used as a spin probe efficiently scavenges cumylperoxyl radical in an aprotic medium via an electron-transfer process, which is significantly accelerated by the presence of scandium ion.

UR - http://www.scopus.com/inward/record.url?scp=34047261841&partnerID=8YFLogxK

U2 - 10.1246/cl.2007.378

DO - 10.1246/cl.2007.378

M3 - Article

AN - SCOPUS:34047261841

SN - 0366-7022

VL - 36

SP - 378

EP - 379

JO - Chemistry Letters

JF - Chemistry Letters

IS - 3

ER -

Scandium ion-accelerated scavenging reaction of cumylperoxyl radical by a cyclic nitroxyl radical via electron transfer

Abstract

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