RuO2 Nanorods on Electrospun Carbon Nanofibers for Supercapacitors

Sohyun Jeon, Ji Hwan Jeong, Hyomin Yoo, Hak Ki Yu, Bo Hye Kim, Myung Hwa Kim

Research output: Contribution to journalArticlepeer-review

103 Scopus citations


RuO2 nanorods on electrospun carbon nanofibers were simply grown by precipitation and recrystallization methods for studying their capacitive behaviors for supercapacitor applications. Recrystallization by heat treatment is carefully performed at various temperatures: 180, 220, and 300 °C. Under optimal growth conditions, application of RuO2-carbon nanofibers annealed at 220 °C with a very low loading concentration of Ru as the electrode material in a KOH aqueous electrolyte leads to a good capacitance capability of 188 F g-1 at a current density of 1 mA cm-2 and a high energy density of 22-15 W h kg-1 in the power density range of 400-4000 W kg-1 for supercapacitor applications. The capacitance of RuO2-carbon nanofibers after 3000 cycles also maintains approximately 93% of its initial value at a discharge current density of 1 mA cm-2. The excellent electrochemical performance of RuO2-carbon nanofibers is mainly attributed to their large surface area with many mesopores as well as their electroactive functional sites, which have the appropriate degree of crystallinity. Therefore, a larger mesopore volume and low-dimensional RuO2 nanorods on carbon nanofibers are beneficial for low internal resistance, leading to ion charge diffusion and charge storage in the bulk of amorphous material.

Original languageEnglish
Pages (from-to)3847-3858
Number of pages12
JournalACS Applied Nano Materials
Issue number4
StatePublished - 24 Apr 2020

Bibliographical note

Funding Information:
This study was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science, ICT & Future Planning (NRF-2020R1A2B5B01002320) and the Basic Science Research Program through the NRF funded by the Ministry of Education (NRF-2018R1A1A03025340 and NRF-2019R1F1A1062799).

Publisher Copyright:
Copyright © 2020 American Chemical Society.


  • crystal phase of RuO
  • electrospun carbon nanofiber
  • microstructure
  • recrystallization temperature
  • supercapacitor


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