Rhodium-catalyzed C-H bond arylation of arenes.

Jean Bouffard; Kenichiro Itami

doi:10.1007/128_2009_12

Rhodium-catalyzed C-H bond arylation of arenes.

Jean Bouffard
, Kenichiro Itami

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Review article › peer-review

121 Scopus citations

Abstract

A review is presented of synthetic methods for the preparation of biaryls by the rhodium-catalyzed C-H bond arylation of arenes with aryl halides (C-H/ C-X couplings), arylmetal reagents (C-H/C-M couplings) and arenes (C-H/C-H couplings), with an emphasis on postulated mechanisms and their implications on reactivity, selectivity and substrate scope.

Original language	English
Pages (from-to)	231-280
Number of pages	50
Journal	Topics in Current Chemistry
Volume	292
DOIs	https://doi.org/10.1007/128_2009_12
State	Published - 2010

Bibliographical note

Funding Information:
This work was supported by the PRESTO program of the Japan Science and Technology Agency (JST), and a Grant-in-Aid for Scientific Research from MEXT and JSPS. J.B. is a recipient of a JSPS Postdoctoral Fellowship.

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10.1007/128_2009_12

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title = "Rhodium-catalyzed C-H bond arylation of arenes.",

abstract = "A review is presented of synthetic methods for the preparation of biaryls by the rhodium-catalyzed C-H bond arylation of arenes with aryl halides (C-H/ C-X couplings), arylmetal reagents (C-H/C-M couplings) and arenes (C-H/C-H couplings), with an emphasis on postulated mechanisms and their implications on reactivity, selectivity and substrate scope.",

author = "Jean Bouffard and Kenichiro Itami",

note = "Funding Information: This work was supported by the PRESTO program of the Japan Science and Technology Agency (JST), and a Grant-in-Aid for Scientific Research from MEXT and JSPS. J.B. is a recipient of a JSPS Postdoctoral Fellowship. ",

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AU - Bouffard, Jean

AU - Itami, Kenichiro

N1 - Funding Information: This work was supported by the PRESTO program of the Japan Science and Technology Agency (JST), and a Grant-in-Aid for Scientific Research from MEXT and JSPS. J.B. is a recipient of a JSPS Postdoctoral Fellowship.

PY - 2010

Y1 - 2010

N2 - A review is presented of synthetic methods for the preparation of biaryls by the rhodium-catalyzed C-H bond arylation of arenes with aryl halides (C-H/ C-X couplings), arylmetal reagents (C-H/C-M couplings) and arenes (C-H/C-H couplings), with an emphasis on postulated mechanisms and their implications on reactivity, selectivity and substrate scope.

AB - A review is presented of synthetic methods for the preparation of biaryls by the rhodium-catalyzed C-H bond arylation of arenes with aryl halides (C-H/ C-X couplings), arylmetal reagents (C-H/C-M couplings) and arenes (C-H/C-H couplings), with an emphasis on postulated mechanisms and their implications on reactivity, selectivity and substrate scope.

UR - https://www.scopus.com/pages/publications/78650176180

U2 - 10.1007/128_2009_12

DO - 10.1007/128_2009_12

M3 - Review article

C2 - 21500409

AN - SCOPUS:78650176180

SN - 0340-1022

VL - 292

SP - 231

EP - 280

JO - Topics in Current Chemistry

JF - Topics in Current Chemistry

ER -

Rhodium-catalyzed C-H bond arylation of arenes.

Abstract

Bibliographical note

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