Abstract
A review is presented of synthetic methods for the preparation of biaryls by the rhodium-catalyzed C-H bond arylation of arenes with aryl halides (C-H/ C-X couplings), arylmetal reagents (C-H/C-M couplings) and arenes (C-H/C-H couplings), with an emphasis on postulated mechanisms and their implications on reactivity, selectivity and substrate scope.
Original language | English |
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Pages (from-to) | 231-280 |
Number of pages | 50 |
Journal | Topics in current chemistry |
Volume | 292 |
DOIs | |
State | Published - 2010 |
Bibliographical note
Funding Information:This work was supported by the PRESTO program of the Japan Science and Technology Agency (JST), and a Grant-in-Aid for Scientific Research from MEXT and JSPS. J.B. is a recipient of a JSPS Postdoctoral Fellowship.