Rhodium-catalyzed C-H bond arylation of arenes.

Jean Bouffard, Kenichiro Itami

Research output: Contribution to journalReview articlepeer-review

115 Scopus citations

Abstract

A review is presented of synthetic methods for the preparation of biaryls by the rhodium-catalyzed C-H bond arylation of arenes with aryl halides (C-H/ C-X couplings), arylmetal reagents (C-H/C-M couplings) and arenes (C-H/C-H couplings), with an emphasis on postulated mechanisms and their implications on reactivity, selectivity and substrate scope.

Original languageEnglish
Pages (from-to)231-280
Number of pages50
JournalTopics in current chemistry
Volume292
DOIs
StatePublished - 2010

Bibliographical note

Funding Information:
This work was supported by the PRESTO program of the Japan Science and Technology Agency (JST), and a Grant-in-Aid for Scientific Research from MEXT and JSPS. J.B. is a recipient of a JSPS Postdoctoral Fellowship.

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