Reversible formation and dispersion of chiral assemblies responding to electron transfer

Junpei Yuasa; Shunichi Fukuzumi

doi:10.1021/ja075149q

Reversible formation and dispersion of chiral assemblies responding to electron transfer

Junpei Yuasa, Shunichi Fukuzumi

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

Electron-transfer reduction of p-benzoquinone (Q) and 1,4-naphthoquinone (NQ), in the presence of [R-(R,R)]-2,6-bis(4,5-dihydro-4-phenyl-2-oxazolinyl)pyridine [Sc³⁺(R)-pybox] results in formation of chiral π-radical anion dimer complexes [(Q•-)₂-(Sc3+(R)-pybox)₂ and (NQ•-)₂-(Sc³⁺(R)-pybox)₂, respectively].

Original language	English
Pages (from-to)	12912-12913
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	129
Issue number	43
DOIs	https://doi.org/10.1021/ja075149q
State	Published - 31 Oct 2007

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title = "Reversible formation and dispersion of chiral assemblies responding to electron transfer",

abstract = "Electron-transfer reduction of p-benzoquinone (Q) and 1,4-naphthoquinone (NQ), in the presence of [R-(R,R)]-2,6-bis(4,5-dihydro-4-phenyl-2-oxazolinyl)pyridine [Sc3+(R)-pybox] results in formation of chiral π-radical anion dimer complexes [(Q•-)2-(Sc3+(R)-pybox)2 and (NQ•-)2-(Sc3+(R)-pybox)2, respectively].",

author = "Junpei Yuasa and Shunichi Fukuzumi",

year = "2007",

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doi = "10.1021/ja075149q",

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journal = "Journal of the American Chemical Society",

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T1 - Reversible formation and dispersion of chiral assemblies responding to electron transfer

AU - Yuasa, Junpei

AU - Fukuzumi, Shunichi

PY - 2007/10/31

Y1 - 2007/10/31

N2 - Electron-transfer reduction of p-benzoquinone (Q) and 1,4-naphthoquinone (NQ), in the presence of [R-(R,R)]-2,6-bis(4,5-dihydro-4-phenyl-2-oxazolinyl)pyridine [Sc3+(R)-pybox] results in formation of chiral π-radical anion dimer complexes [(Q•-)2-(Sc3+(R)-pybox)2 and (NQ•-)2-(Sc3+(R)-pybox)2, respectively].

AB - Electron-transfer reduction of p-benzoquinone (Q) and 1,4-naphthoquinone (NQ), in the presence of [R-(R,R)]-2,6-bis(4,5-dihydro-4-phenyl-2-oxazolinyl)pyridine [Sc3+(R)-pybox] results in formation of chiral π-radical anion dimer complexes [(Q•-)2-(Sc3+(R)-pybox)2 and (NQ•-)2-(Sc3+(R)-pybox)2, respectively].

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SP - 12912

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

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ER -

Reversible formation and dispersion of chiral assemblies responding to electron transfer

Abstract

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