[Re12CS17(CN)6]n- (n = 6, 8): A sulfido-cyanide rhenium cluster with an interstitial carbon atom

Yuri V. Mironov; Nikolai G. Naumov; Svetlana G. Kozlova; Sung Jin Kim; Vladimir E. Fedorov

doi:10.1002/anie.200501911

[Re₁₂CS₁₇(CN)₆]^n- (n = 6, 8): A sulfido-cyanide rhenium cluster with an interstitial carbon atom

Yuri V. Mironov, Nikolai G. Naumov, Svetlana G. Kozlova, Sung Jin Kim, Vladimir E. Fedorov

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

48 Scopus citations

Abstract

Cyanide clusters [Re₁₂CS₁₇(CN)₆] ^n- (n = 8 or 6), which may be used to form polymeric material, have been prepared by treating ReS₂ with molten KCN at 750°C. The cluster unit comprises two {Re₆} octahedra connected by three μ₂-S bridges and one interstitial μ₆-C atom (see picture). (Figure Presented).

Original language	English
Pages (from-to)	6867-6871
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	44
Issue number	42
DOIs	https://doi.org/10.1002/anie.200501911
State	Published - 28 Oct 2005

Keywords

Cluster compounds
Cyanides
Density functional calculations
Electronic structure
Rhenium

Access to Document

10.1002/anie.200501911

Cite this

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title = "[Re12CS17(CN)6]n- (n = 6, 8): A sulfido-cyanide rhenium cluster with an interstitial carbon atom",

abstract = "Cyanide clusters [Re12CS17(CN)6] n- (n = 8 or 6), which may be used to form polymeric material, have been prepared by treating ReS2 with molten KCN at 750°C. The cluster unit comprises two {Re6} octahedra connected by three μ2-S bridges and one interstitial μ6-C atom (see picture). (Figure Presented).",

keywords = "Cluster compounds, Cyanides, Density functional calculations, Electronic structure, Rhenium",

author = "Mironov, {Yuri V.} and Naumov, {Nikolai G.} and Kozlova, {Svetlana G.} and Kim, {Sung Jin} and Fedorov, {Vladimir E.}",

year = "2005",

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T1 - [Re12CS17(CN)6]n- (n = 6, 8)

T2 - A sulfido-cyanide rhenium cluster with an interstitial carbon atom

AU - Mironov, Yuri V.

AU - Naumov, Nikolai G.

AU - Kozlova, Svetlana G.

AU - Kim, Sung Jin

AU - Fedorov, Vladimir E.

PY - 2005/10/28

Y1 - 2005/10/28

N2 - Cyanide clusters [Re12CS17(CN)6] n- (n = 8 or 6), which may be used to form polymeric material, have been prepared by treating ReS2 with molten KCN at 750°C. The cluster unit comprises two {Re6} octahedra connected by three μ2-S bridges and one interstitial μ6-C atom (see picture). (Figure Presented).

AB - Cyanide clusters [Re12CS17(CN)6] n- (n = 8 or 6), which may be used to form polymeric material, have been prepared by treating ReS2 with molten KCN at 750°C. The cluster unit comprises two {Re6} octahedra connected by three μ2-S bridges and one interstitial μ6-C atom (see picture). (Figure Presented).

KW - Cluster compounds

KW - Cyanides

KW - Density functional calculations

KW - Electronic structure

KW - Rhenium

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DO - 10.1002/anie.200501911

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JF - Angewandte Chemie - International Edition

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