TY - JOUR
T1 - Reductive Electrophotocatalysis
T2 - Merging Electricity and Light to Achieve Extreme Reduction Potentials
AU - Kim, Hyunwoo
AU - Kim, Hyungjun
AU - Lambert, Tristan H.
AU - Lin, Song
N1 - Publisher Copyright:
Copyright © 2020 American Chemical Society.
PY - 2020/2/5
Y1 - 2020/2/5
N2 - We describe a new electrophotocatalytic strategy that harnesses the power of light and electricity to generate an excited radical anion with a reducing potential of -3.2 V vs SCE, which can be used to activate substrates with very high reduction potentials (Ered ≈ -1.9 to -2.9 V). The resultant aryl radicals can be engaged in various synthetically useful transformations to furnish arylboronate, arylstannane, and biaryl products.
AB - We describe a new electrophotocatalytic strategy that harnesses the power of light and electricity to generate an excited radical anion with a reducing potential of -3.2 V vs SCE, which can be used to activate substrates with very high reduction potentials (Ered ≈ -1.9 to -2.9 V). The resultant aryl radicals can be engaged in various synthetically useful transformations to furnish arylboronate, arylstannane, and biaryl products.
UR - http://www.scopus.com/inward/record.url?scp=85078667042&partnerID=8YFLogxK
U2 - 10.1021/jacs.9b10678
DO - 10.1021/jacs.9b10678
M3 - Article
C2 - 31951390
AN - SCOPUS:85078667042
SN - 0002-7863
VL - 142
SP - 2087
EP - 2092
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
IS - 5
ER -