Redox behavior of cyclo[6]pyrrole in the formation of a uranyl complex

Patricia J. Melfi; Kuk Kim Sung; Tae Lee Jeong; Frédéric Bolze; Daniel Seidel; Vincent M. Lynch; Jacqueline M. Veauthier; Andrew J. Gaunt; Mary P. Neu; Zhongping Ou; Karl M. Kadish; Shunichi Fukuzumi; Kei Ohkubo; Jonathan L. Sessler

doi:10.1021/ic700781t

Redox behavior of cyclo[6]pyrrole in the formation of a uranyl complex

Patricia J. Melfi
, Kuk Kim Sung
, Tae Lee Jeong
, Frédéric Bolze
, Daniel Seidel
, Vincent M. Lynch
, Jacqueline M. Veauthier
, Andrew J. Gaunt
, Mary P. Neu
, Zhongping Ou
, Karl M. Kadish
, Shunichi Fukuzumi
, Kei Ohkubo
, Jonathan L. Sessler

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

48 Scopus citations

Abstract

A uranyl complex, the first metal complex to be formed from the cyclo[n]pyrrole series of expanded porphyrins, is formed when cyclo[6]pyrrole is treated with the uranyl cation under aerobic conditions. Spectroscopic, spectroelectrochemical, and electron spin resonance data of this species are consistent with the ligand in the complex being oxidized to an antiaromatic form.

Original language	English
Pages (from-to)	5143-5145
Number of pages	3
Journal	Inorganic Chemistry
Volume	46
Issue number	13
DOIs	https://doi.org/10.1021/ic700781t
State	Published - 25 Jun 2007

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@article{125b609cf85d4329b4d5454e26fed59e,

title = "Redox behavior of cyclo[6]pyrrole in the formation of a uranyl complex",

abstract = "A uranyl complex, the first metal complex to be formed from the cyclo[n]pyrrole series of expanded porphyrins, is formed when cyclo[6]pyrrole is treated with the uranyl cation under aerobic conditions. Spectroscopic, spectroelectrochemical, and electron spin resonance data of this species are consistent with the ligand in the complex being oxidized to an antiaromatic form.",

author = "Melfi, \{Patricia J.\} and Sung, \{Kuk Kim\} and Jeong, \{Tae Lee\} and Fr{\'e}d{\'e}ric Bolze and Daniel Seidel and Lynch, \{Vincent M.\} and Veauthier, \{Jacqueline M.\} and Gaunt, \{Andrew J.\} and Neu, \{Mary P.\} and Zhongping Ou and Kadish, \{Karl M.\} and Shunichi Fukuzumi and Kei Ohkubo and Sessler, \{Jonathan L.\}",

year = "2007",

month = jun,

day = "25",

doi = "10.1021/ic700781t",

language = "English",

volume = "46",

pages = "5143--5145",

journal = "Inorganic Chemistry",

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publisher = "American Chemical Society",

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TY - JOUR

T1 - Redox behavior of cyclo[6]pyrrole in the formation of a uranyl complex

AU - Melfi, Patricia J.

AU - Sung, Kuk Kim

AU - Jeong, Tae Lee

AU - Bolze, Frédéric

AU - Seidel, Daniel

AU - Lynch, Vincent M.

AU - Veauthier, Jacqueline M.

AU - Gaunt, Andrew J.

AU - Neu, Mary P.

AU - Ou, Zhongping

AU - Kadish, Karl M.

AU - Fukuzumi, Shunichi

AU - Ohkubo, Kei

AU - Sessler, Jonathan L.

PY - 2007/6/25

Y1 - 2007/6/25

N2 - A uranyl complex, the first metal complex to be formed from the cyclo[n]pyrrole series of expanded porphyrins, is formed when cyclo[6]pyrrole is treated with the uranyl cation under aerobic conditions. Spectroscopic, spectroelectrochemical, and electron spin resonance data of this species are consistent with the ligand in the complex being oxidized to an antiaromatic form.

AB - A uranyl complex, the first metal complex to be formed from the cyclo[n]pyrrole series of expanded porphyrins, is formed when cyclo[6]pyrrole is treated with the uranyl cation under aerobic conditions. Spectroscopic, spectroelectrochemical, and electron spin resonance data of this species are consistent with the ligand in the complex being oxidized to an antiaromatic form.

UR - https://www.scopus.com/pages/publications/34447312852

U2 - 10.1021/ic700781t

DO - 10.1021/ic700781t

M3 - Article

AN - SCOPUS:34447312852

SN - 0020-1669

VL - 46

SP - 5143

EP - 5145

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 13

ER -

Redox behavior of cyclo[6]pyrrole in the formation of a uranyl complex

Abstract

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