Receptor that can capture a discrete monohydrated fluoride anion

Punidha Sokkalingam, Se Young Kee, Youngmee Kim, Sung Jin Kim, Phil Ho Lee, Chang Hee Lee

Research output: Contribution to journalArticlepeer-review

17 Scopus citations

Abstract

A 'picket calix[4]pyrrole' bearing a well-defined binding domain has allowed the stabilization of a monohydrated fluoride anion. The monohydrated F- was observed only when CsF (not the TBAF) was treated with a host in aqueous acetonitrile. The structure of the receptor-bound, monohydrated F- was fully characterized by single crystal X-ray diffraction analysis as well as by low temperature 1H and 19F NMR spectroscopy. Further analysis revealed that the complex formed a three-dimensional, salt mediated organic framework in the solid state.

Original languageEnglish
Pages (from-to)6234-6237
Number of pages4
JournalOrganic Letters
Volume14
Issue number24
DOIs
StatePublished - 21 Dec 2012

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