Reactivity comparison of high-valent iron(iv)-oxo complexes bearing N-tetramethylated cyclam ligands with different ring size

Seungwoo Hong; Hee So; Heejung Yoon; Kyung Bin Cho; Yong Min Lee; Shunichi Fukuzumi; Wonwoo Nam

doi:10.1039/c3dt50750e

Reactivity comparison of high-valent iron(iv)-oxo complexes bearing N-tetramethylated cyclam ligands with different ring size

Seungwoo Hong, Hee So, Heejung Yoon, Kyung Bin Cho, Yong Min Lee, Shunichi Fukuzumi, Wonwoo Nam

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

56 Scopus citations

Abstract

The ring size effect of macrocyclic TMC ligands in nonheme iron(iv)-oxo complexes has been examined in hydrogen atom transfer (HAT) and oxygen atom transfer (OAT) reactions; an iron(iv)-oxo complex bearing a smaller TMC ligand is more reactive in both HAT and OAT reactions, resulting from its high Fe ^IV/III redox potential.

Original language	English
Pages (from-to)	7842-7845
Number of pages	4
Journal	Dalton Transactions
Volume	42
Issue number	22
DOIs	https://doi.org/10.1039/c3dt50750e
State	Published - 14 Jun 2013

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abstract = "The ring size effect of macrocyclic TMC ligands in nonheme iron(iv)-oxo complexes has been examined in hydrogen atom transfer (HAT) and oxygen atom transfer (OAT) reactions; an iron(iv)-oxo complex bearing a smaller TMC ligand is more reactive in both HAT and OAT reactions, resulting from its high Fe IV/III redox potential.",

author = "Seungwoo Hong and Hee So and Heejung Yoon and Cho, {Kyung Bin} and Lee, {Yong Min} and Shunichi Fukuzumi and Wonwoo Nam",

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T1 - Reactivity comparison of high-valent iron(iv)-oxo complexes bearing N-tetramethylated cyclam ligands with different ring size

AU - Hong, Seungwoo

AU - So, Hee

AU - Yoon, Heejung

AU - Cho, Kyung Bin

AU - Lee, Yong Min

AU - Fukuzumi, Shunichi

AU - Nam, Wonwoo

PY - 2013/6/14

Y1 - 2013/6/14

N2 - The ring size effect of macrocyclic TMC ligands in nonheme iron(iv)-oxo complexes has been examined in hydrogen atom transfer (HAT) and oxygen atom transfer (OAT) reactions; an iron(iv)-oxo complex bearing a smaller TMC ligand is more reactive in both HAT and OAT reactions, resulting from its high Fe IV/III redox potential.

AB - The ring size effect of macrocyclic TMC ligands in nonheme iron(iv)-oxo complexes has been examined in hydrogen atom transfer (HAT) and oxygen atom transfer (OAT) reactions; an iron(iv)-oxo complex bearing a smaller TMC ligand is more reactive in both HAT and OAT reactions, resulting from its high Fe IV/III redox potential.

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U2 - 10.1039/c3dt50750e

DO - 10.1039/c3dt50750e

M3 - Article

C2 - 23588673

AN - SCOPUS:84878069737

SN - 1477-9226

VL - 42

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EP - 7845

JO - Dalton Transactions

JF - Dalton Transactions

IS - 22

ER -

Reactivity comparison of high-valent iron(iv)-oxo complexes bearing N-tetramethylated cyclam ligands with different ring size

Abstract

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