Reactivity comparison of high-valent iron(iv)-oxo complexes bearing N-tetramethylated cyclam ligands with different ring size

Seungwoo Hong, Hee So, Heejung Yoon, Kyung Bin Cho, Yong Min Lee, Shunichi Fukuzumi, Wonwoo Nam

Research output: Contribution to journalArticlepeer-review

47 Scopus citations

Abstract

The ring size effect of macrocyclic TMC ligands in nonheme iron(iv)-oxo complexes has been examined in hydrogen atom transfer (HAT) and oxygen atom transfer (OAT) reactions; an iron(iv)-oxo complex bearing a smaller TMC ligand is more reactive in both HAT and OAT reactions, resulting from its high Fe IV/III redox potential.

Original languageEnglish
Pages (from-to)7842-7845
Number of pages4
JournalDalton Transactions
Volume42
Issue number22
DOIs
StatePublished - 14 Jun 2013

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