Rational design of a phthalocyanine-perylenediimide dyad with a long-lived charge-separated state

Vicente M. Blas-Ferrando; Javier Ortiz; Latifa Bouissane; Kei Ohkubo; Shunichi Fukuzumi; Fernando Fernández-Lázaro; Ángela Sastre-Santos

doi:10.1039/c2cc31087b

Rational design of a phthalocyanine-perylenediimide dyad with a long-lived charge-separated state

Vicente M. Blas-Ferrando
, Javier Ortiz
, Latifa Bouissane
, Kei Ohkubo
, Shunichi Fukuzumi
, Fernando Fernández-Lázaro
, Ángela Sastre-Santos

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

57 Scopus citations

Abstract

A new ZnPc-PDI dyad presenting for the first time a charge-separated state lower in energy than the triplet excited state of the ZnPc and PDI has been synthesized. The rational design implies the substitution of the ZnPc with phenoxy groups and the bay substitution of the PDI with sulfonyl substituents. The lifetime of the charge-separated state was 72 μs.

Original language	English
Pages (from-to)	6241-6243
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	50
DOIs	https://doi.org/10.1039/c2cc31087b
State	Published - 28 May 2012

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abstract = "A new ZnPc-PDI dyad presenting for the first time a charge-separated state lower in energy than the triplet excited state of the ZnPc and PDI has been synthesized. The rational design implies the substitution of the ZnPc with phenoxy groups and the bay substitution of the PDI with sulfonyl substituents. The lifetime of the charge-separated state was 72 μs.",

author = "Blas-Ferrando, \{Vicente M.\} and Javier Ortiz and Latifa Bouissane and Kei Ohkubo and Shunichi Fukuzumi and Fernando Fern{\'a}ndez-L{\'a}zaro and {\'A}ngela Sastre-Santos",

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AU - Blas-Ferrando, Vicente M.

AU - Ortiz, Javier

AU - Bouissane, Latifa

AU - Ohkubo, Kei

AU - Fukuzumi, Shunichi

AU - Fernández-Lázaro, Fernando

AU - Sastre-Santos, Ángela

PY - 2012/5/28

Y1 - 2012/5/28

N2 - A new ZnPc-PDI dyad presenting for the first time a charge-separated state lower in energy than the triplet excited state of the ZnPc and PDI has been synthesized. The rational design implies the substitution of the ZnPc with phenoxy groups and the bay substitution of the PDI with sulfonyl substituents. The lifetime of the charge-separated state was 72 μs.

AB - A new ZnPc-PDI dyad presenting for the first time a charge-separated state lower in energy than the triplet excited state of the ZnPc and PDI has been synthesized. The rational design implies the substitution of the ZnPc with phenoxy groups and the bay substitution of the PDI with sulfonyl substituents. The lifetime of the charge-separated state was 72 μs.

UR - https://www.scopus.com/pages/publications/84861638915

U2 - 10.1039/c2cc31087b

DO - 10.1039/c2cc31087b

M3 - Article

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SN - 1359-7345

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EP - 6243

JO - Chemical Communications

JF - Chemical Communications

IS - 50

ER -

Rational design of a phthalocyanine-perylenediimide dyad with a long-lived charge-separated state

Abstract

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