TY - JOUR
T1 - Rational design of a phthalocyanine-perylenediimide dyad with a long-lived charge-separated state
AU - Blas-Ferrando, Vicente M.
AU - Ortiz, Javier
AU - Bouissane, Latifa
AU - Ohkubo, Kei
AU - Fukuzumi, Shunichi
AU - Fernández-Lázaro, Fernando
AU - Sastre-Santos, Ángela
PY - 2012/5/28
Y1 - 2012/5/28
N2 - A new ZnPc-PDI dyad presenting for the first time a charge-separated state lower in energy than the triplet excited state of the ZnPc and PDI has been synthesized. The rational design implies the substitution of the ZnPc with phenoxy groups and the bay substitution of the PDI with sulfonyl substituents. The lifetime of the charge-separated state was 72 μs.
AB - A new ZnPc-PDI dyad presenting for the first time a charge-separated state lower in energy than the triplet excited state of the ZnPc and PDI has been synthesized. The rational design implies the substitution of the ZnPc with phenoxy groups and the bay substitution of the PDI with sulfonyl substituents. The lifetime of the charge-separated state was 72 μs.
UR - http://www.scopus.com/inward/record.url?scp=84861638915&partnerID=8YFLogxK
U2 - 10.1039/c2cc31087b
DO - 10.1039/c2cc31087b
M3 - Article
C2 - 22595768
AN - SCOPUS:84861638915
SN - 1359-7345
VL - 48
SP - 6241
EP - 6243
JO - Chemical Communications
JF - Chemical Communications
IS - 50
ER -