Ratiometric fluorescent chemosensor for silver ion at physiological pH

Fang Wang; Raju Nandhakumar; Jong Hun Moon; Kwan Mook Kim; Jin Yong Lee; Juyoung Yoon

doi:10.1021/ic1018967

Ratiometric fluorescent chemosensor for silver ion at physiological pH

Fang Wang, Raju Nandhakumar, Jong Hun Moon, Kwan Mook Kim, Jin Yong Lee, Juyoung Yoon

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

127 Scopus citations

Abstract

Bis-pyrene derivative 1, bearing two pyrene and pyridine groups, was synthesized as a ratiometric fluorescent chemosensor for Ag⁺ in aqueous solution. Fluorescent chemosensor 1 displayed a selective ratiometric change with Ag⁺, which was attributed to the excimer-monomer emissions of pyrenes. A mechanism for the binding mode was proposed based on fluorescence changes, NMR experiments, and theoretical calculations.

Original language	English
Pages (from-to)	2240-2245
Number of pages	6
Journal	Inorganic Chemistry
Volume	50
Issue number	6
DOIs	https://doi.org/10.1021/ic1018967
State	Published - 21 Mar 2011

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title = "Ratiometric fluorescent chemosensor for silver ion at physiological pH",

abstract = "Bis-pyrene derivative 1, bearing two pyrene and pyridine groups, was synthesized as a ratiometric fluorescent chemosensor for Ag+ in aqueous solution. Fluorescent chemosensor 1 displayed a selective ratiometric change with Ag+, which was attributed to the excimer-monomer emissions of pyrenes. A mechanism for the binding mode was proposed based on fluorescence changes, NMR experiments, and theoretical calculations.",

author = "Fang Wang and Raju Nandhakumar and Moon, \{Jong Hun\} and Kim, \{Kwan Mook\} and Lee, \{Jin Yong\} and Juyoung Yoon",

year = "2011",

month = mar,

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doi = "10.1021/ic1018967",

language = "English",

volume = "50",

pages = "2240--2245",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

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T1 - Ratiometric fluorescent chemosensor for silver ion at physiological pH

AU - Wang, Fang

AU - Nandhakumar, Raju

AU - Moon, Jong Hun

AU - Kim, Kwan Mook

AU - Lee, Jin Yong

AU - Yoon, Juyoung

PY - 2011/3/21

Y1 - 2011/3/21

N2 - Bis-pyrene derivative 1, bearing two pyrene and pyridine groups, was synthesized as a ratiometric fluorescent chemosensor for Ag+ in aqueous solution. Fluorescent chemosensor 1 displayed a selective ratiometric change with Ag+, which was attributed to the excimer-monomer emissions of pyrenes. A mechanism for the binding mode was proposed based on fluorescence changes, NMR experiments, and theoretical calculations.

AB - Bis-pyrene derivative 1, bearing two pyrene and pyridine groups, was synthesized as a ratiometric fluorescent chemosensor for Ag+ in aqueous solution. Fluorescent chemosensor 1 displayed a selective ratiometric change with Ag+, which was attributed to the excimer-monomer emissions of pyrenes. A mechanism for the binding mode was proposed based on fluorescence changes, NMR experiments, and theoretical calculations.

UR - https://www.scopus.com/pages/publications/79954450739

U2 - 10.1021/ic1018967

DO - 10.1021/ic1018967

M3 - Article

C2 - 21291199

AN - SCOPUS:79954450739

SN - 0020-1669

VL - 50

SP - 2240

EP - 2245

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 6

ER -

Ratiometric fluorescent chemosensor for silver ion at physiological pH

Abstract

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