Quantitative evaluation of Lewis acidity of zinc ion with tetradentate tripodal ligands in formation of the superoxide complexes

Hideki Ohtsu; Shunichi Fukuzumi

doi:10.1246/cl.2001.920

Quantitative evaluation of Lewis acidity of zinc ion with tetradentate tripodal ligands in formation of the superoxide complexes

Hideki Ohtsu
, Shunichi Fukuzumi

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

A series of Zn(II)-superoxide complexes containing tetradentate tripodal ligands are generated in the reactions between Zn(II) complexes and superoxide which is produced by the photoinduced reduction of dioxygen by dimeric 1-benzyl-1,4-dihydronicotinamide. The Zn(II)-superoxide complexes have been characterized spectroscopically in order to evaluate the Lewis acidity of Zn(II) ion depending on the ligands used as Cu,Zn-SOD models.

Original language	English
Pages (from-to)	920-921
Number of pages	2
Journal	Chemistry Letters
Issue number	9
DOIs	https://doi.org/10.1246/cl.2001.920
State	Published - 2001

Access to Document

10.1246/cl.2001.920

Cite this

@article{1d0bf576337f4b8fae6d2ad060ca7dfe,

title = "Quantitative evaluation of Lewis acidity of zinc ion with tetradentate tripodal ligands in formation of the superoxide complexes",

abstract = "A series of Zn(II)-superoxide complexes containing tetradentate tripodal ligands are generated in the reactions between Zn(II) complexes and superoxide which is produced by the photoinduced reduction of dioxygen by dimeric 1-benzyl-1,4-dihydronicotinamide. The Zn(II)-superoxide complexes have been characterized spectroscopically in order to evaluate the Lewis acidity of Zn(II) ion depending on the ligands used as Cu,Zn-SOD models.",

author = "Hideki Ohtsu and Shunichi Fukuzumi",

year = "2001",

doi = "10.1246/cl.2001.920",

language = "English",

pages = "920--921",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Oxford University Press",

number = "9",

}

TY - JOUR

T1 - Quantitative evaluation of Lewis acidity of zinc ion with tetradentate tripodal ligands in formation of the superoxide complexes

AU - Ohtsu, Hideki

AU - Fukuzumi, Shunichi

PY - 2001

Y1 - 2001

N2 - A series of Zn(II)-superoxide complexes containing tetradentate tripodal ligands are generated in the reactions between Zn(II) complexes and superoxide which is produced by the photoinduced reduction of dioxygen by dimeric 1-benzyl-1,4-dihydronicotinamide. The Zn(II)-superoxide complexes have been characterized spectroscopically in order to evaluate the Lewis acidity of Zn(II) ion depending on the ligands used as Cu,Zn-SOD models.

AB - A series of Zn(II)-superoxide complexes containing tetradentate tripodal ligands are generated in the reactions between Zn(II) complexes and superoxide which is produced by the photoinduced reduction of dioxygen by dimeric 1-benzyl-1,4-dihydronicotinamide. The Zn(II)-superoxide complexes have been characterized spectroscopically in order to evaluate the Lewis acidity of Zn(II) ion depending on the ligands used as Cu,Zn-SOD models.

UR - https://www.scopus.com/pages/publications/0035540074

U2 - 10.1246/cl.2001.920

DO - 10.1246/cl.2001.920

M3 - Article

AN - SCOPUS:0035540074

SN - 0366-7022

SP - 920

EP - 921

JO - Chemistry Letters

JF - Chemistry Letters

IS - 9

ER -

Quantitative evaluation of Lewis acidity of zinc ion with tetradentate tripodal ligands in formation of the superoxide complexes

Abstract

Access to Document

Fingerprint

Cite this