Quantitative evaluation of Lewis acidity of zinc ion with tetradentate tripodal ligands in formation of the superoxide complexes

Hideki Ohtsu; Shunichi Fukuzumi

doi:10.1246/cl.2001.920

Quantitative evaluation of Lewis acidity of zinc ion with tetradentate tripodal ligands in formation of the superoxide complexes

Hideki Ohtsu, Shunichi Fukuzumi

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

A series of Zn(II)-superoxide complexes containing tetradentate tripodal ligands are generated in the reactions between Zn(II) complexes and superoxide which is produced by the photoinduced reduction of dioxygen by dimeric 1-benzyl-1,4-dihydronicotinamide. The Zn(II)-superoxide complexes have been characterized spectroscopically in order to evaluate the Lewis acidity of Zn(II) ion depending on the ligands used as Cu,Zn-SOD models.

Original language	English
Pages (from-to)	920-921
Number of pages	2
Journal	Chemistry Letters
Issue number	9
DOIs	https://doi.org/10.1246/cl.2001.920
State	Published - 2001

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title = "Quantitative evaluation of Lewis acidity of zinc ion with tetradentate tripodal ligands in formation of the superoxide complexes",

abstract = "A series of Zn(II)-superoxide complexes containing tetradentate tripodal ligands are generated in the reactions between Zn(II) complexes and superoxide which is produced by the photoinduced reduction of dioxygen by dimeric 1-benzyl-1,4-dihydronicotinamide. The Zn(II)-superoxide complexes have been characterized spectroscopically in order to evaluate the Lewis acidity of Zn(II) ion depending on the ligands used as Cu,Zn-SOD models.",

author = "Hideki Ohtsu and Shunichi Fukuzumi",

year = "2001",

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AU - Fukuzumi, Shunichi

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AB - A series of Zn(II)-superoxide complexes containing tetradentate tripodal ligands are generated in the reactions between Zn(II) complexes and superoxide which is produced by the photoinduced reduction of dioxygen by dimeric 1-benzyl-1,4-dihydronicotinamide. The Zn(II)-superoxide complexes have been characterized spectroscopically in order to evaluate the Lewis acidity of Zn(II) ion depending on the ligands used as Cu,Zn-SOD models.

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DO - 10.1246/cl.2001.920

M3 - Article

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JO - Chemistry Letters

JF - Chemistry Letters

IS - 9

ER -

Quantitative evaluation of Lewis acidity of zinc ion with tetradentate tripodal ligands in formation of the superoxide complexes

Abstract

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