Protonated iron-phthalocyanine complex used for cathode material of a hydrogen peroxide fuel cell operated under acidic conditions

Yusuke Yamada; Sho Yoshida; Tatsuhiko Honda; Shunichi Fukuzumi

doi:10.1039/c1ee01587g

Protonated iron-phthalocyanine complex used for cathode material of a hydrogen peroxide fuel cell operated under acidic conditions

Yusuke Yamada, Sho Yoshida, Tatsuhiko Honda, Shunichi Fukuzumi

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

137 Scopus citations

Abstract

An iron-phthalocyanine complex was utilized as a cathode for constructing a one-compartment hydrogen peroxide fuel cell operated under acidic conditions for the first time. The protonation to the phthalocyanine ligand is crucial to exhibit high activity toward hydrogen peroxide reduction. Nafion® coating of the anode improved the stability of the fuel cell.

Original language	English
Pages (from-to)	2822-2825
Number of pages	4
Journal	Energy and Environmental Science
Volume	4
Issue number	8
DOIs	https://doi.org/10.1039/c1ee01587g
State	Published - Aug 2011

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title = "Protonated iron-phthalocyanine complex used for cathode material of a hydrogen peroxide fuel cell operated under acidic conditions",

abstract = "An iron-phthalocyanine complex was utilized as a cathode for constructing a one-compartment hydrogen peroxide fuel cell operated under acidic conditions for the first time. The protonation to the phthalocyanine ligand is crucial to exhibit high activity toward hydrogen peroxide reduction. Nafion{\textregistered} coating of the anode improved the stability of the fuel cell.",

author = "Yusuke Yamada and Sho Yoshida and Tatsuhiko Honda and Shunichi Fukuzumi",

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AU - Yoshida, Sho

AU - Honda, Tatsuhiko

AU - Fukuzumi, Shunichi

PY - 2011/8

Y1 - 2011/8

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AB - An iron-phthalocyanine complex was utilized as a cathode for constructing a one-compartment hydrogen peroxide fuel cell operated under acidic conditions for the first time. The protonation to the phthalocyanine ligand is crucial to exhibit high activity toward hydrogen peroxide reduction. Nafion® coating of the anode improved the stability of the fuel cell.

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JO - Energy and Environmental Science

JF - Energy and Environmental Science

IS - 8

ER -

Protonated iron-phthalocyanine complex used for cathode material of a hydrogen peroxide fuel cell operated under acidic conditions

Abstract

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