Proton-promoted disproportionation of iron(v)-imido TAML to iron(v)-imido TAML cation radical and iron(iv) TAML

Xiaoyan Lu, Yong Min Lee, Mi Sook Seo, Wonwoo Nam

Research output: Contribution to journalArticlepeer-review

6 Scopus citations

Abstract

The present study reports the first example of a proton-promoted disproportionation reaction of a non-heme iron(v)-imido TAML (1) complex to give an iron(v)-imido TAML cation radical (2) and an iron(iv) TAML (3) upon addition of acids. Detailed mechanistic investigations revealed that two molecules of1react with one proton to yield2and [FeIV(NHTs)(TAML)](4), followed by the reaction of4with another proton to afford3and NH2Ts.

Original languageEnglish
Pages (from-to)11207-11210
Number of pages4
JournalChemical Communications
Volume56
Issue number76
DOIs
StatePublished - 28 Sep 2020

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