Production of an ultra-long-lived charge-separated state in a zinc chlorin-C60 dyad by one-step photoinduced electron transfer

Kei Ohkubo; Hiroaki Kotani; Jianguo Shao; Zhongping Ou; Karl M. Kadish; Guolin Li; Ravindra K. Pandey; Mamoru Fujitsuka; Osamu Ito; Hiroshi Imahori; Shunichi Fukuzumi

doi:10.1002/anie.200352870

Production of an ultra-long-lived charge-separated state in a zinc chlorin-C₆₀ dyad by one-step photoinduced electron transfer

Kei Ohkubo, Hiroaki Kotani, Jianguo Shao, Zhongping Ou, Karl M. Kadish, Guolin Li, Ravindra K. Pandey, Mamoru Fujitsuka, Osamu Ito, Hiroshi Imahori, Shunichi Fukuzumi

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

227 Scopus citations

Abstract

Long live the state! Photoexcitation of a zinc chlorin-fullerene dyad with a short linkage results in the formation of the ultra-long-lived charge-separated (CS) state by a one-step photoinduced electron transfer without loss of energy, which is inevitable for charge separation by multistep electron-transfer processes. The lifetime of the charge-separated state was 120 s in frozen PhCN at -150°C (see picture).

Original language	English
Pages (from-to)	853-856
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	43
Issue number	7
DOIs	https://doi.org/10.1002/anie.200352870
State	Published - 6 Feb 2004

Keywords

Charge separation
Chlorin
Electron transfer
Fullerenes
Photosynthesis

Access to Document

10.1002/anie.200352870

Cite this

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title = "Production of an ultra-long-lived charge-separated state in a zinc chlorin-C60 dyad by one-step photoinduced electron transfer",

abstract = "Long live the state! Photoexcitation of a zinc chlorin-fullerene dyad with a short linkage results in the formation of the ultra-long-lived charge-separated (CS) state by a one-step photoinduced electron transfer without loss of energy, which is inevitable for charge separation by multistep electron-transfer processes. The lifetime of the charge-separated state was 120 s in frozen PhCN at -150°C (see picture).",

keywords = "Charge separation, Chlorin, Electron transfer, Fullerenes, Photosynthesis",

author = "Kei Ohkubo and Hiroaki Kotani and Jianguo Shao and Zhongping Ou and Kadish, \{Karl M.\} and Guolin Li and Pandey, \{Ravindra K.\} and Mamoru Fujitsuka and Osamu Ito and Hiroshi Imahori and Shunichi Fukuzumi",

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language = "English",

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T1 - Production of an ultra-long-lived charge-separated state in a zinc chlorin-C60 dyad by one-step photoinduced electron transfer

AU - Ohkubo, Kei

AU - Kotani, Hiroaki

AU - Shao, Jianguo

AU - Ou, Zhongping

AU - Kadish, Karl M.

AU - Li, Guolin

AU - Pandey, Ravindra K.

AU - Fujitsuka, Mamoru

AU - Ito, Osamu

AU - Imahori, Hiroshi

AU - Fukuzumi, Shunichi

PY - 2004/2/6

Y1 - 2004/2/6

N2 - Long live the state! Photoexcitation of a zinc chlorin-fullerene dyad with a short linkage results in the formation of the ultra-long-lived charge-separated (CS) state by a one-step photoinduced electron transfer without loss of energy, which is inevitable for charge separation by multistep electron-transfer processes. The lifetime of the charge-separated state was 120 s in frozen PhCN at -150°C (see picture).

AB - Long live the state! Photoexcitation of a zinc chlorin-fullerene dyad with a short linkage results in the formation of the ultra-long-lived charge-separated (CS) state by a one-step photoinduced electron transfer without loss of energy, which is inevitable for charge separation by multistep electron-transfer processes. The lifetime of the charge-separated state was 120 s in frozen PhCN at -150°C (see picture).

KW - Charge separation

KW - Chlorin

KW - Electron transfer

KW - Fullerenes

KW - Photosynthesis

UR - https://www.scopus.com/pages/publications/2642516986

U2 - 10.1002/anie.200352870

DO - 10.1002/anie.200352870

M3 - Article

C2 - 14767957

AN - SCOPUS:2642516986

SN - 1433-7851

VL - 43

SP - 853

EP - 856

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 7