Post-synthetic ligand cyclization in metal-organic frameworks through functional group connection with regioisomerism

Dasom Kim; Haneul Yoo; Kyunghwan Kim; Dongwook Kim; Ki Tae Kim; Cheoljae Kim; Jin Yeong Kim; Hoi Ri Moon; Min Kim

doi:10.1039/d2cc01031c

Post-synthetic ligand cyclization in metal-organic frameworks through functional group connection with regioisomerism

Dasom Kim
, Haneul Yoo
, Kyunghwan Kim
, Dongwook Kim
, Ki Tae Kim
, Cheoljae Kim
, Jin Yeong Kim
, Hoi Ri Moon
, Min Kim

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

A covalent connection between two orthogonal functional groups (-NH₂ and -OH) in metal-organic frameworks (MOFs) has been developed. This post-synthetic ligand cyclization (PSLC) was successfully demonstrated to synthesize a benzoxazole-functionalized MOF from a Zr-based UiO-66-2,3-(NH₂)(OH) under microwave irradiation. In contrast, the regioisomeric UiO-66-2,5-(NH₂)(OH) only produces a non-cyclized formamide-functionalized MOF.

Original language	English
Journal	Chemical Communications
DOIs	https://doi.org/10.1039/d2cc01031c
State	Accepted/In press - 2022

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© 2022 The Royal Society of Chemistry.

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title = "Post-synthetic ligand cyclization in metal-organic frameworks through functional group connection with regioisomerism",

abstract = "A covalent connection between two orthogonal functional groups (-NH2 and -OH) in metal-organic frameworks (MOFs) has been developed. This post-synthetic ligand cyclization (PSLC) was successfully demonstrated to synthesize a benzoxazole-functionalized MOF from a Zr-based UiO-66-2,3-(NH2)(OH) under microwave irradiation. In contrast, the regioisomeric UiO-66-2,5-(NH2)(OH) only produces a non-cyclized formamide-functionalized MOF.",

author = "Dasom Kim and Haneul Yoo and Kyunghwan Kim and Dongwook Kim and Kim, \{Ki Tae\} and Cheoljae Kim and Kim, \{Jin Yeong\} and Moon, \{Hoi Ri\} and Min Kim",

note = "Publisher Copyright: {\textcopyright} 2022 The Royal Society of Chemistry.",

year = "2022",

doi = "10.1039/d2cc01031c",

language = "English",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Post-synthetic ligand cyclization in metal-organic frameworks through functional group connection with regioisomerism

AU - Kim, Dasom

AU - Yoo, Haneul

AU - Kim, Kyunghwan

AU - Kim, Dongwook

AU - Kim, Ki Tae

AU - Kim, Cheoljae

AU - Kim, Jin Yeong

AU - Moon, Hoi Ri

AU - Kim, Min

PY - 2022

Y1 - 2022

N2 - A covalent connection between two orthogonal functional groups (-NH2 and -OH) in metal-organic frameworks (MOFs) has been developed. This post-synthetic ligand cyclization (PSLC) was successfully demonstrated to synthesize a benzoxazole-functionalized MOF from a Zr-based UiO-66-2,3-(NH2)(OH) under microwave irradiation. In contrast, the regioisomeric UiO-66-2,5-(NH2)(OH) only produces a non-cyclized formamide-functionalized MOF.

AB - A covalent connection between two orthogonal functional groups (-NH2 and -OH) in metal-organic frameworks (MOFs) has been developed. This post-synthetic ligand cyclization (PSLC) was successfully demonstrated to synthesize a benzoxazole-functionalized MOF from a Zr-based UiO-66-2,3-(NH2)(OH) under microwave irradiation. In contrast, the regioisomeric UiO-66-2,5-(NH2)(OH) only produces a non-cyclized formamide-functionalized MOF.

UR - https://www.scopus.com/pages/publications/85128780080

U2 - 10.1039/d2cc01031c

DO - 10.1039/d2cc01031c

M3 - Article

C2 - 35415736

AN - SCOPUS:85128780080

SN - 1359-7345

JO - Chemical Communications

JF - Chemical Communications

ER -

Post-synthetic ligand cyclization in metal-organic frameworks through functional group connection with regioisomerism

Abstract

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