Post-synthetic ligand cyclization in metal-organic frameworks through functional group connection with regioisomerism

Dasom Kim; Haneul Yoo; Kyunghwan Kim; Dongwook Kim; Ki Tae Kim; Cheoljae Kim; Jin Yeong Kim; Hoi Ri Moon; Min Kim

doi:10.1039/d2cc01031c

Post-synthetic ligand cyclization in metal-organic frameworks through functional group connection with regioisomerism

Dasom Kim, Haneul Yoo, Kyunghwan Kim, Dongwook Kim, Ki Tae Kim, Cheoljae Kim, Jin Yeong Kim, Hoi Ri Moon, Min Kim

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

A covalent connection between two orthogonal functional groups (-NH₂ and -OH) in metal-organic frameworks (MOFs) has been developed. This post-synthetic ligand cyclization (PSLC) was successfully demonstrated to synthesize a benzoxazole-functionalized MOF from a Zr-based UiO-66-2,3-(NH₂)(OH) under microwave irradiation. In contrast, the regioisomeric UiO-66-2,5-(NH₂)(OH) only produces a non-cyclized formamide-functionalized MOF.

Original language	English
Journal	Chemical Communications
DOIs	https://doi.org/10.1039/d2cc01031c
State	Accepted/In press - 2022

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© 2022 The Royal Society of Chemistry.

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@article{b78a9d8adb3e42a380256a2d4359e7a2,

title = "Post-synthetic ligand cyclization in metal-organic frameworks through functional group connection with regioisomerism",

abstract = "A covalent connection between two orthogonal functional groups (-NH2 and -OH) in metal-organic frameworks (MOFs) has been developed. This post-synthetic ligand cyclization (PSLC) was successfully demonstrated to synthesize a benzoxazole-functionalized MOF from a Zr-based UiO-66-2,3-(NH2)(OH) under microwave irradiation. In contrast, the regioisomeric UiO-66-2,5-(NH2)(OH) only produces a non-cyclized formamide-functionalized MOF.",

author = "Dasom Kim and Haneul Yoo and Kyunghwan Kim and Dongwook Kim and Kim, {Ki Tae} and Cheoljae Kim and Kim, {Jin Yeong} and Moon, {Hoi Ri} and Min Kim",

note = "Publisher Copyright: {\textcopyright} 2022 The Royal Society of Chemistry.",

year = "2022",

doi = "10.1039/d2cc01031c",

language = "English",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Post-synthetic ligand cyclization in metal-organic frameworks through functional group connection with regioisomerism

AU - Kim, Dasom

AU - Yoo, Haneul

AU - Kim, Kyunghwan

AU - Kim, Dongwook

AU - Kim, Ki Tae

AU - Kim, Cheoljae

AU - Kim, Jin Yeong

AU - Moon, Hoi Ri

AU - Kim, Min

PY - 2022

Y1 - 2022

N2 - A covalent connection between two orthogonal functional groups (-NH2 and -OH) in metal-organic frameworks (MOFs) has been developed. This post-synthetic ligand cyclization (PSLC) was successfully demonstrated to synthesize a benzoxazole-functionalized MOF from a Zr-based UiO-66-2,3-(NH2)(OH) under microwave irradiation. In contrast, the regioisomeric UiO-66-2,5-(NH2)(OH) only produces a non-cyclized formamide-functionalized MOF.

AB - A covalent connection between two orthogonal functional groups (-NH2 and -OH) in metal-organic frameworks (MOFs) has been developed. This post-synthetic ligand cyclization (PSLC) was successfully demonstrated to synthesize a benzoxazole-functionalized MOF from a Zr-based UiO-66-2,3-(NH2)(OH) under microwave irradiation. In contrast, the regioisomeric UiO-66-2,5-(NH2)(OH) only produces a non-cyclized formamide-functionalized MOF.

UR - http://www.scopus.com/inward/record.url?scp=85128780080&partnerID=8YFLogxK

U2 - 10.1039/d2cc01031c

DO - 10.1039/d2cc01031c

M3 - Article

C2 - 35415736

AN - SCOPUS:85128780080

SN - 1359-7345

JO - Chemical Communications

JF - Chemical Communications

ER -

Post-synthetic ligand cyclization in metal-organic frameworks through functional group connection with regioisomerism

Abstract

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