Porous metal-organic framework with coordinatively unsaturated Mn II sites:sorption properties for various gases

Ri Moon Hoi; Norihito Kobayashi; Paik Suh Myunghyun

doi:10.1021/ic0611948

Porous metal-organic framework with coordinatively unsaturated Mn ^II sites:sorption properties for various gases

Ri Moon Hoi, Norihito Kobayashi, Paik Suh Myunghyun

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

141 Scopus citations

Abstract

A 3D porous metal-organic framework generating 1D channels, [Mn(NDC)(DEF)]_n (1), has been prepared from the solvothermal reaction of Mn^II and 2,6-naphthalenedicarboxylic acid (H₂NDC) in diethylformamide (DEF). When DEF molecules coordinating Mn^II, which occupy the channels, are removed from 1 by heating the crystal of 1 at 250°C under vacuum for 18 h, structural change occurs as evidenced by X-ray powder diffraction patterns. Desolvated solid [Mn(NDC)]_n (2), which contains coordinatively unsaturated Mn^II sites, reveals remarkable sorption capabilities for N₂, H₂, CO₂, and CH ₄ gases and exhibits type I sorption behavior indicative of permanent microporosity.

Original language	English
Pages (from-to)	8672-8676
Number of pages	5
Journal	Inorganic Chemistry
Volume	45
Issue number	21
DOIs	https://doi.org/10.1021/ic0611948
State	Published - 16 Oct 2006

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title = "Porous metal-organic framework with coordinatively unsaturated Mn II sites:sorption properties for various gases",

abstract = "A 3D porous metal-organic framework generating 1D channels, [Mn(NDC)(DEF)]n (1), has been prepared from the solvothermal reaction of MnII and 2,6-naphthalenedicarboxylic acid (H2NDC) in diethylformamide (DEF). When DEF molecules coordinating MnII, which occupy the channels, are removed from 1 by heating the crystal of 1 at 250°C under vacuum for 18 h, structural change occurs as evidenced by X-ray powder diffraction patterns. Desolvated solid [Mn(NDC)]n (2), which contains coordinatively unsaturated MnII sites, reveals remarkable sorption capabilities for N2, H2, CO2, and CH 4 gases and exhibits type I sorption behavior indicative of permanent microporosity.",

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AU - Hoi, Ri Moon

AU - Kobayashi, Norihito

AU - Myunghyun, Paik Suh

PY - 2006/10/16

Y1 - 2006/10/16

N2 - A 3D porous metal-organic framework generating 1D channels, [Mn(NDC)(DEF)]n (1), has been prepared from the solvothermal reaction of MnII and 2,6-naphthalenedicarboxylic acid (H2NDC) in diethylformamide (DEF). When DEF molecules coordinating MnII, which occupy the channels, are removed from 1 by heating the crystal of 1 at 250°C under vacuum for 18 h, structural change occurs as evidenced by X-ray powder diffraction patterns. Desolvated solid [Mn(NDC)]n (2), which contains coordinatively unsaturated MnII sites, reveals remarkable sorption capabilities for N2, H2, CO2, and CH 4 gases and exhibits type I sorption behavior indicative of permanent microporosity.

AB - A 3D porous metal-organic framework generating 1D channels, [Mn(NDC)(DEF)]n (1), has been prepared from the solvothermal reaction of MnII and 2,6-naphthalenedicarboxylic acid (H2NDC) in diethylformamide (DEF). When DEF molecules coordinating MnII, which occupy the channels, are removed from 1 by heating the crystal of 1 at 250°C under vacuum for 18 h, structural change occurs as evidenced by X-ray powder diffraction patterns. Desolvated solid [Mn(NDC)]n (2), which contains coordinatively unsaturated MnII sites, reveals remarkable sorption capabilities for N2, H2, CO2, and CH 4 gases and exhibits type I sorption behavior indicative of permanent microporosity.

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 21

ER -

Porous metal-organic framework with coordinatively unsaturated Mn II sites:sorption properties for various gases

Abstract

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Porous metal-organic framework with coordinatively unsaturated Mn ^II sites:sorption properties for various gases