Porous metal-organic framework with coordinatively unsaturated Mn II sites:sorption properties for various gases

Ri Moon Hoi; Norihito Kobayashi; Paik Suh Myunghyun

doi:10.1021/ic0611948

Porous metal-organic framework with coordinatively unsaturated Mn ^II sites:sorption properties for various gases

Ri Moon Hoi, Norihito Kobayashi, Paik Suh Myunghyun

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

137 Scopus citations

Abstract

A 3D porous metal-organic framework generating 1D channels, [Mn(NDC)(DEF)]_n (1), has been prepared from the solvothermal reaction of Mn^II and 2,6-naphthalenedicarboxylic acid (H₂NDC) in diethylformamide (DEF). When DEF molecules coordinating Mn^II, which occupy the channels, are removed from 1 by heating the crystal of 1 at 250°C under vacuum for 18 h, structural change occurs as evidenced by X-ray powder diffraction patterns. Desolvated solid [Mn(NDC)]_n (2), which contains coordinatively unsaturated Mn^II sites, reveals remarkable sorption capabilities for N₂, H₂, CO₂, and CH ₄ gases and exhibits type I sorption behavior indicative of permanent microporosity.

Original language	English
Pages (from-to)	8672-8676
Number of pages	5
Journal	Inorganic Chemistry
Volume	45
Issue number	21
DOIs	https://doi.org/10.1021/ic0611948
State	Published - 16 Oct 2006

Access to Document

10.1021/ic0611948

Cite this

@article{a8f3cfc8883a4dd1b1507eaa5b03a586,

title = "Porous metal-organic framework with coordinatively unsaturated Mn II sites:sorption properties for various gases",

abstract = "A 3D porous metal-organic framework generating 1D channels, [Mn(NDC)(DEF)]n (1), has been prepared from the solvothermal reaction of MnII and 2,6-naphthalenedicarboxylic acid (H2NDC) in diethylformamide (DEF). When DEF molecules coordinating MnII, which occupy the channels, are removed from 1 by heating the crystal of 1 at 250°C under vacuum for 18 h, structural change occurs as evidenced by X-ray powder diffraction patterns. Desolvated solid [Mn(NDC)]n (2), which contains coordinatively unsaturated MnII sites, reveals remarkable sorption capabilities for N2, H2, CO2, and CH 4 gases and exhibits type I sorption behavior indicative of permanent microporosity.",

author = "Hoi, {Ri Moon} and Norihito Kobayashi and Myunghyun, {Paik Suh}",

year = "2006",

month = oct,

day = "16",

doi = "10.1021/ic0611948",

language = "English",

volume = "45",

pages = "8672--8676",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "21",

}

TY - JOUR

T1 - Porous metal-organic framework with coordinatively unsaturated Mn II sites:sorption properties for various gases

AU - Hoi, Ri Moon

AU - Kobayashi, Norihito

AU - Myunghyun, Paik Suh

PY - 2006/10/16

Y1 - 2006/10/16

N2 - A 3D porous metal-organic framework generating 1D channels, [Mn(NDC)(DEF)]n (1), has been prepared from the solvothermal reaction of MnII and 2,6-naphthalenedicarboxylic acid (H2NDC) in diethylformamide (DEF). When DEF molecules coordinating MnII, which occupy the channels, are removed from 1 by heating the crystal of 1 at 250°C under vacuum for 18 h, structural change occurs as evidenced by X-ray powder diffraction patterns. Desolvated solid [Mn(NDC)]n (2), which contains coordinatively unsaturated MnII sites, reveals remarkable sorption capabilities for N2, H2, CO2, and CH 4 gases and exhibits type I sorption behavior indicative of permanent microporosity.

AB - A 3D porous metal-organic framework generating 1D channels, [Mn(NDC)(DEF)]n (1), has been prepared from the solvothermal reaction of MnII and 2,6-naphthalenedicarboxylic acid (H2NDC) in diethylformamide (DEF). When DEF molecules coordinating MnII, which occupy the channels, are removed from 1 by heating the crystal of 1 at 250°C under vacuum for 18 h, structural change occurs as evidenced by X-ray powder diffraction patterns. Desolvated solid [Mn(NDC)]n (2), which contains coordinatively unsaturated MnII sites, reveals remarkable sorption capabilities for N2, H2, CO2, and CH 4 gases and exhibits type I sorption behavior indicative of permanent microporosity.

UR - http://www.scopus.com/inward/record.url?scp=33750378404&partnerID=8YFLogxK

U2 - 10.1021/ic0611948

DO - 10.1021/ic0611948

M3 - Article

AN - SCOPUS:33750378404

SN - 0020-1669

VL - 45

SP - 8672

EP - 8676

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 21

ER -

Porous metal-organic framework with coordinatively unsaturated Mn II sites:sorption properties for various gases

Abstract

Access to Document

Fingerprint

Cite this

Porous metal-organic framework with coordinatively unsaturated Mn ^II sites:sorption properties for various gases