Photoluminescent materials based on PMMA and a highly-emissive octahedral molybdenum metal cluster complex

Olga A. Efremova; Konstantin A. Brylev; Yuri A. Vorotnikov; Lucie Vejsadová; Michael A. Shestopalov; Gwen F. Chimonides; Petr Mikes; Paul D. Topham; Sung Jin Kim; Noboru Kitamura; Andrew J. Sutherland

doi:10.1039/c5tc03204k

Photoluminescent materials based on PMMA and a highly-emissive octahedral molybdenum metal cluster complex

Olga A. Efremova, Konstantin A. Brylev, Yuri A. Vorotnikov, Lucie Vejsadová, Michael A. Shestopalov, Gwen F. Chimonides, Petr Mikes, Paul D. Topham, Sung Jin Kim, Noboru Kitamura, Andrew J. Sutherland

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

45 Scopus citations

Abstract

Materials that combine photoluminescence, optical transparency and facile processability are of high importance in many applications. This article reports on the development of photoluminescent poly(methyl methacrylate) materials based on novel highly emissive anionic molybdenum cluster complex [{Mo₆I₈}(OTs)₆]^2- (where OTs^- is the p-toluenesulfonate ion). The materials were obtained by both solution and bulk copolymerisation of methyl methacrylate and (dMDAEMA)₂[{Mo₆I₈}(OTs)₆], where dMDAEMA⁺ is the polymerisable cation [2-(methacryloyloxy)ethyl]dimethyl-dodecylammonium. Evaluation of the resultant hybrid materials showed that one could combine the excellent photoluminescent properties of the cluster complex with the transparency and processability of PMMA.

Original language	English
Pages (from-to)	497-503
Number of pages	7
Journal	Journal of Materials Chemistry C
Volume	4
Issue number	3
DOIs	https://doi.org/10.1039/c5tc03204k
State	Published - 2016

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Publisher Copyright:
© The Royal Society of Chemistry 2016.

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Efremova, O. A., Brylev, K. A., Vorotnikov, Y. A., Vejsadová, L., Shestopalov, M. A., Chimonides, G. F., Mikes, P., Topham, P. D., Kim, S. J., Kitamura, N., & Sutherland, A. J. (2016). Photoluminescent materials based on PMMA and a highly-emissive octahedral molybdenum metal cluster complex. Journal of Materials Chemistry C, 4(3), 497-503. https://doi.org/10.1039/c5tc03204k

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title = "Photoluminescent materials based on PMMA and a highly-emissive octahedral molybdenum metal cluster complex",

abstract = "Materials that combine photoluminescence, optical transparency and facile processability are of high importance in many applications. This article reports on the development of photoluminescent poly(methyl methacrylate) materials based on novel highly emissive anionic molybdenum cluster complex [{Mo6I8}(OTs)6]2- (where OTs- is the p-toluenesulfonate ion). The materials were obtained by both solution and bulk copolymerisation of methyl methacrylate and (dMDAEMA)2[{Mo6I8}(OTs)6], where dMDAEMA+ is the polymerisable cation [2-(methacryloyloxy)ethyl]dimethyl-dodecylammonium. Evaluation of the resultant hybrid materials showed that one could combine the excellent photoluminescent properties of the cluster complex with the transparency and processability of PMMA.",

author = "Efremova, {Olga A.} and Brylev, {Konstantin A.} and Vorotnikov, {Yuri A.} and Lucie Vejsadov{\'a} and Shestopalov, {Michael A.} and Chimonides, {Gwen F.} and Petr Mikes and Topham, {Paul D.} and Kim, {Sung Jin} and Noboru Kitamura and Sutherland, {Andrew J.}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2016.",

year = "2016",

doi = "10.1039/c5tc03204k",

language = "English",

volume = "4",

pages = "497--503",

journal = "Journal of Materials Chemistry C",

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publisher = "Royal Society of Chemistry",

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T1 - Photoluminescent materials based on PMMA and a highly-emissive octahedral molybdenum metal cluster complex

AU - Efremova, Olga A.

AU - Brylev, Konstantin A.

AU - Vorotnikov, Yuri A.

AU - Vejsadová, Lucie

AU - Shestopalov, Michael A.

AU - Chimonides, Gwen F.

AU - Mikes, Petr

AU - Topham, Paul D.

AU - Kim, Sung Jin

AU - Kitamura, Noboru

AU - Sutherland, Andrew J.

PY - 2016

Y1 - 2016

N2 - Materials that combine photoluminescence, optical transparency and facile processability are of high importance in many applications. This article reports on the development of photoluminescent poly(methyl methacrylate) materials based on novel highly emissive anionic molybdenum cluster complex [{Mo6I8}(OTs)6]2- (where OTs- is the p-toluenesulfonate ion). The materials were obtained by both solution and bulk copolymerisation of methyl methacrylate and (dMDAEMA)2[{Mo6I8}(OTs)6], where dMDAEMA+ is the polymerisable cation [2-(methacryloyloxy)ethyl]dimethyl-dodecylammonium. Evaluation of the resultant hybrid materials showed that one could combine the excellent photoluminescent properties of the cluster complex with the transparency and processability of PMMA.

AB - Materials that combine photoluminescence, optical transparency and facile processability are of high importance in many applications. This article reports on the development of photoluminescent poly(methyl methacrylate) materials based on novel highly emissive anionic molybdenum cluster complex [{Mo6I8}(OTs)6]2- (where OTs- is the p-toluenesulfonate ion). The materials were obtained by both solution and bulk copolymerisation of methyl methacrylate and (dMDAEMA)2[{Mo6I8}(OTs)6], where dMDAEMA+ is the polymerisable cation [2-(methacryloyloxy)ethyl]dimethyl-dodecylammonium. Evaluation of the resultant hybrid materials showed that one could combine the excellent photoluminescent properties of the cluster complex with the transparency and processability of PMMA.

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DO - 10.1039/c5tc03204k

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VL - 4

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EP - 503

JO - Journal of Materials Chemistry C

JF - Journal of Materials Chemistry C

IS - 3

ER -

Photoluminescent materials based on PMMA and a highly-emissive octahedral molybdenum metal cluster complex

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