Photoluminescent and electroluminescent properties of DCM-1 dispersed poly(p-phenylene vinylene) derivatives

Guolun Zhong; Kyungkon Kim; Dong Won Lee; Jung Il Jin

doi:10.1016/j.synthmet.2006.04.009

Photoluminescent and electroluminescent properties of DCM-1 dispersed poly(p-phenylene vinylene) derivatives

Guolun Zhong, Kyungkon Kim, Dong Won Lee, Jung Il Jin

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

The single layer devices utilizing poly[2-(carbazol-9-yl)-5-(2-ethylhcxyloxy)-1,4-phenylene vinylene] (CzEh-PPV) and poly[2-{4-[5-(4-tert-butylphenyl)-l,3,4-oxadiazolyl]-phenyl}-5-(2-ethythexyloxy)-l,4-phenylene vinylene] (OxdEh-PPV) doped with varying weight percent of 4-(dicyanomethylene)-2-methyl-6-[p-(dimethylamino)styryl]-4H-pyran (DCM-1) were fabricated and their photo luminescence (PL) and electroluminescence (EL) properties were discussed in this investigation. The PL spectra of DCM-1 doped polymers show that the emission is mostly from DCM-1 and Förster energy transfer may occur between DCM-1 and the two polymers. On the other hand, field-dependence of the emission spectra of EL devices was observed in detail. For the CzEh-PPV/DCM-1, the emission at the wavelength of 534 nm remains unchanged as the level of DCM-1 increases, whereas the peak at 572 nm is intensified with increasing both the additive level and applied electric field. For the OxdEh-PPV/DCM-1, the main peak is red-shift as the level of DCM-1 increases and blue-shift as the applied electric field does.

Original language	English
Pages (from-to)	731-735
Number of pages	5
Journal	Synthetic Metals
Volume	156
Issue number	9-10
DOIs	https://doi.org/10.1016/j.synthmet.2006.04.009
State	Published - 5 May 2006

Bibliographical note

Funding Information:
This research was supported by the Ministry of Science and Technology, Republic of Korea and the Korea Science and Engineering Foundation, through the Center for Electro- and Photo-Responsive Molecules, Korea University. G. Zhong and K. Kim wish to acknowledge the support by the Ministry of Education through the Brain Korea 21 program. The financial support from NIT, Zhejiang University is also grateful.

Keywords

DCM-1 doping
Electroluminescence
Field-dependence
Förster energy transfer
Photoluminescence
Poly(phenylene vinylene) derivatives

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10.1016/j.synthmet.2006.04.009

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@article{36344214ce2a4867a6825dfe8e20c431,

title = "Photoluminescent and electroluminescent properties of DCM-1 dispersed poly(p-phenylene vinylene) derivatives",

abstract = "The single layer devices utilizing poly[2-(carbazol-9-yl)-5-(2-ethylhcxyloxy)-1,4-phenylene vinylene] (CzEh-PPV) and poly[2-{4-[5-(4-tert-butylphenyl)-l,3,4-oxadiazolyl]-phenyl}-5-(2-ethythexyloxy)-l,4-phenylene vinylene] (OxdEh-PPV) doped with varying weight percent of 4-(dicyanomethylene)-2-methyl-6-[p-(dimethylamino)styryl]-4H-pyran (DCM-1) were fabricated and their photo luminescence (PL) and electroluminescence (EL) properties were discussed in this investigation. The PL spectra of DCM-1 doped polymers show that the emission is mostly from DCM-1 and F{\"o}rster energy transfer may occur between DCM-1 and the two polymers. On the other hand, field-dependence of the emission spectra of EL devices was observed in detail. For the CzEh-PPV/DCM-1, the emission at the wavelength of 534 nm remains unchanged as the level of DCM-1 increases, whereas the peak at 572 nm is intensified with increasing both the additive level and applied electric field. For the OxdEh-PPV/DCM-1, the main peak is red-shift as the level of DCM-1 increases and blue-shift as the applied electric field does.",

keywords = "DCM-1 doping, Electroluminescence, Field-dependence, F{\"o}rster energy transfer, Photoluminescence, Poly(phenylene vinylene) derivatives",

author = "Guolun Zhong and Kyungkon Kim and Lee, {Dong Won} and Jin, {Jung Il}",

note = "Funding Information: This research was supported by the Ministry of Science and Technology, Republic of Korea and the Korea Science and Engineering Foundation, through the Center for Electro- and Photo-Responsive Molecules, Korea University. G. Zhong and K. Kim wish to acknowledge the support by the Ministry of Education through the Brain Korea 21 program. The financial support from NIT, Zhejiang University is also grateful.",

year = "2006",

month = may,

day = "5",

doi = "10.1016/j.synthmet.2006.04.009",

language = "English",

volume = "156",

pages = "731--735",

journal = "Synthetic Metals",

issn = "0379-6779",

publisher = "Elsevier BV",

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TY - JOUR

T1 - Photoluminescent and electroluminescent properties of DCM-1 dispersed poly(p-phenylene vinylene) derivatives

AU - Zhong, Guolun

AU - Kim, Kyungkon

AU - Lee, Dong Won

AU - Jin, Jung Il

N1 - Funding Information: This research was supported by the Ministry of Science and Technology, Republic of Korea and the Korea Science and Engineering Foundation, through the Center for Electro- and Photo-Responsive Molecules, Korea University. G. Zhong and K. Kim wish to acknowledge the support by the Ministry of Education through the Brain Korea 21 program. The financial support from NIT, Zhejiang University is also grateful.

PY - 2006/5/5

Y1 - 2006/5/5

N2 - The single layer devices utilizing poly[2-(carbazol-9-yl)-5-(2-ethylhcxyloxy)-1,4-phenylene vinylene] (CzEh-PPV) and poly[2-{4-[5-(4-tert-butylphenyl)-l,3,4-oxadiazolyl]-phenyl}-5-(2-ethythexyloxy)-l,4-phenylene vinylene] (OxdEh-PPV) doped with varying weight percent of 4-(dicyanomethylene)-2-methyl-6-[p-(dimethylamino)styryl]-4H-pyran (DCM-1) were fabricated and their photo luminescence (PL) and electroluminescence (EL) properties were discussed in this investigation. The PL spectra of DCM-1 doped polymers show that the emission is mostly from DCM-1 and Förster energy transfer may occur between DCM-1 and the two polymers. On the other hand, field-dependence of the emission spectra of EL devices was observed in detail. For the CzEh-PPV/DCM-1, the emission at the wavelength of 534 nm remains unchanged as the level of DCM-1 increases, whereas the peak at 572 nm is intensified with increasing both the additive level and applied electric field. For the OxdEh-PPV/DCM-1, the main peak is red-shift as the level of DCM-1 increases and blue-shift as the applied electric field does.

AB - The single layer devices utilizing poly[2-(carbazol-9-yl)-5-(2-ethylhcxyloxy)-1,4-phenylene vinylene] (CzEh-PPV) and poly[2-{4-[5-(4-tert-butylphenyl)-l,3,4-oxadiazolyl]-phenyl}-5-(2-ethythexyloxy)-l,4-phenylene vinylene] (OxdEh-PPV) doped with varying weight percent of 4-(dicyanomethylene)-2-methyl-6-[p-(dimethylamino)styryl]-4H-pyran (DCM-1) were fabricated and their photo luminescence (PL) and electroluminescence (EL) properties were discussed in this investigation. The PL spectra of DCM-1 doped polymers show that the emission is mostly from DCM-1 and Förster energy transfer may occur between DCM-1 and the two polymers. On the other hand, field-dependence of the emission spectra of EL devices was observed in detail. For the CzEh-PPV/DCM-1, the emission at the wavelength of 534 nm remains unchanged as the level of DCM-1 increases, whereas the peak at 572 nm is intensified with increasing both the additive level and applied electric field. For the OxdEh-PPV/DCM-1, the main peak is red-shift as the level of DCM-1 increases and blue-shift as the applied electric field does.

KW - DCM-1 doping

KW - Electroluminescence

KW - Field-dependence

KW - Förster energy transfer

KW - Photoluminescence

KW - Poly(phenylene vinylene) derivatives

UR - http://www.scopus.com/inward/record.url?scp=33744906552&partnerID=8YFLogxK

U2 - 10.1016/j.synthmet.2006.04.009

DO - 10.1016/j.synthmet.2006.04.009

M3 - Article

AN - SCOPUS:33744906552

SN - 0379-6779

VL - 156

SP - 731

EP - 735

JO - Synthetic Metals

JF - Synthetic Metals

IS - 9-10

ER -

Photoluminescent and electroluminescent properties of DCM-1 dispersed poly(p-phenylene vinylene) derivatives

Abstract

Bibliographical note

Keywords

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