Photochemical and thermal isomerization of a ruthenium(II)-alloxazine complex involving an unusual coordination mode

Soushi Miyazaki; Takahiko Kojima; Shunichi Fukuzumi

doi:10.1021/ja077954a

Photochemical and thermal isomerization of a ruthenium(II)-alloxazine complex involving an unusual coordination mode

Soushi Miyazaki, Takahiko Kojima, Shunichi Fukuzumi

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

41 Scopus citations

Abstract

A Ru(II) complex having a flavin analogue as a ligand in a unusual coordination mode exhibits a photochemical and thermal isomerization; the bistability of the complex is attained by chelate effect and intramolecular CH⋯O interaction.

Original language	English
Pages (from-to)	1556-1557
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	130
Issue number	5
DOIs	https://doi.org/10.1021/ja077954a
State	Published - 6 Feb 2008

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title = "Photochemical and thermal isomerization of a ruthenium(II)-alloxazine complex involving an unusual coordination mode",

abstract = "A Ru(II) complex having a flavin analogue as a ligand in a unusual coordination mode exhibits a photochemical and thermal isomerization; the bistability of the complex is attained by chelate effect and intramolecular CH⋯O interaction.",

author = "Soushi Miyazaki and Takahiko Kojima and Shunichi Fukuzumi",

year = "2008",

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T1 - Photochemical and thermal isomerization of a ruthenium(II)-alloxazine complex involving an unusual coordination mode

AU - Miyazaki, Soushi

AU - Kojima, Takahiko

AU - Fukuzumi, Shunichi

PY - 2008/2/6

Y1 - 2008/2/6

N2 - A Ru(II) complex having a flavin analogue as a ligand in a unusual coordination mode exhibits a photochemical and thermal isomerization; the bistability of the complex is attained by chelate effect and intramolecular CH⋯O interaction.

AB - A Ru(II) complex having a flavin analogue as a ligand in a unusual coordination mode exhibits a photochemical and thermal isomerization; the bistability of the complex is attained by chelate effect and intramolecular CH⋯O interaction.

UR - https://www.scopus.com/pages/publications/38949146003

U2 - 10.1021/ja077954a

DO - 10.1021/ja077954a

M3 - Article

C2 - 18189403

AN - SCOPUS:38949146003

SN - 0002-7863

VL - 130

SP - 1556

EP - 1557

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 5

ER -

Photochemical and thermal isomerization of a ruthenium(II)-alloxazine complex involving an unusual coordination mode

Abstract

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