Photocatalytic production of hydrogen by disproportionation of one-electron-reduced rhodium and iridium-ruthenium complexes in water

Shunichi Fukuzumi; Takeshi Kobayashi; Tomoyoshi Suenobu

doi:10.1002/anie.201004876

Photocatalytic production of hydrogen by disproportionation of one-electron-reduced rhodium and iridium-ruthenium complexes in water

Shunichi Fukuzumi, Takeshi Kobayashi, Tomoyoshi Suenobu

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

117 Scopus citations

Abstract

One at a time: A rhodium aqua complex and a heterodinuclear iridium-ruthenium complex (see picture) act as effective catalysts for the photocatalytic two-electron reduction of protons. Hydrogen is produced with the aid of a photosensitizer and an electron donor by disproportionation of the corresponding one-electron-reduced metal complexes.

Original language	English
Pages (from-to)	728-731
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	50
Issue number	3
DOIs	https://doi.org/10.1002/anie.201004876
State	Published - 17 Jan 2011

Keywords

electron transfer
homogeneous catalysis
hydrogen
iridium
rhodium

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10.1002/anie.201004876

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abstract = "One at a time: A rhodium aqua complex and a heterodinuclear iridium-ruthenium complex (see picture) act as effective catalysts for the photocatalytic two-electron reduction of protons. Hydrogen is produced with the aid of a photosensitizer and an electron donor by disproportionation of the corresponding one-electron-reduced metal complexes.",

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AU - Kobayashi, Takeshi

AU - Suenobu, Tomoyoshi

PY - 2011/1/17

Y1 - 2011/1/17

N2 - One at a time: A rhodium aqua complex and a heterodinuclear iridium-ruthenium complex (see picture) act as effective catalysts for the photocatalytic two-electron reduction of protons. Hydrogen is produced with the aid of a photosensitizer and an electron donor by disproportionation of the corresponding one-electron-reduced metal complexes.

AB - One at a time: A rhodium aqua complex and a heterodinuclear iridium-ruthenium complex (see picture) act as effective catalysts for the photocatalytic two-electron reduction of protons. Hydrogen is produced with the aid of a photosensitizer and an electron donor by disproportionation of the corresponding one-electron-reduced metal complexes.

KW - electron transfer

KW - homogeneous catalysis

KW - hydrogen

KW - iridium

KW - rhodium

UR - https://www.scopus.com/pages/publications/78651405883

U2 - 10.1002/anie.201004876

DO - 10.1002/anie.201004876

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ER -

Photocatalytic production of hydrogen by disproportionation of one-electron-reduced rhodium and iridium-ruthenium complexes in water

Abstract

Keywords

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