Photocatalytic production of hydrogen by disproportionation of one-electron-reduced rhodium and iridium-ruthenium complexes in water

Shunichi Fukuzumi; Takeshi Kobayashi; Tomoyoshi Suenobu

doi:10.1002/anie.201004876

Photocatalytic production of hydrogen by disproportionation of one-electron-reduced rhodium and iridium-ruthenium complexes in water

Shunichi Fukuzumi, Takeshi Kobayashi, Tomoyoshi Suenobu

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

111 Scopus citations

Abstract

One at a time: A rhodium aqua complex and a heterodinuclear iridium-ruthenium complex (see picture) act as effective catalysts for the photocatalytic two-electron reduction of protons. Hydrogen is produced with the aid of a photosensitizer and an electron donor by disproportionation of the corresponding one-electron-reduced metal complexes.

Original language	English
Pages (from-to)	728-731
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	50
Issue number	3
DOIs	https://doi.org/10.1002/anie.201004876
State	Published - 17 Jan 2011

Keywords

electron transfer
homogeneous catalysis
hydrogen
iridium
rhodium

Access to Document

10.1002/anie.201004876

Cite this

@article{20112c2fdc8c4948a203f41a28518fe5,

title = "Photocatalytic production of hydrogen by disproportionation of one-electron-reduced rhodium and iridium-ruthenium complexes in water",

abstract = "One at a time: A rhodium aqua complex and a heterodinuclear iridium-ruthenium complex (see picture) act as effective catalysts for the photocatalytic two-electron reduction of protons. Hydrogen is produced with the aid of a photosensitizer and an electron donor by disproportionation of the corresponding one-electron-reduced metal complexes.",

keywords = "electron transfer, homogeneous catalysis, hydrogen, iridium, rhodium",

author = "Shunichi Fukuzumi and Takeshi Kobayashi and Tomoyoshi Suenobu",

year = "2011",

month = jan,

day = "17",

doi = "10.1002/anie.201004876",

language = "English",

volume = "50",

pages = "728--731",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "3",

}

TY - JOUR

T1 - Photocatalytic production of hydrogen by disproportionation of one-electron-reduced rhodium and iridium-ruthenium complexes in water

AU - Fukuzumi, Shunichi

AU - Kobayashi, Takeshi

AU - Suenobu, Tomoyoshi

PY - 2011/1/17

Y1 - 2011/1/17

N2 - One at a time: A rhodium aqua complex and a heterodinuclear iridium-ruthenium complex (see picture) act as effective catalysts for the photocatalytic two-electron reduction of protons. Hydrogen is produced with the aid of a photosensitizer and an electron donor by disproportionation of the corresponding one-electron-reduced metal complexes.

AB - One at a time: A rhodium aqua complex and a heterodinuclear iridium-ruthenium complex (see picture) act as effective catalysts for the photocatalytic two-electron reduction of protons. Hydrogen is produced with the aid of a photosensitizer and an electron donor by disproportionation of the corresponding one-electron-reduced metal complexes.

KW - electron transfer

KW - homogeneous catalysis

KW - hydrogen

KW - iridium

KW - rhodium

UR - http://www.scopus.com/inward/record.url?scp=78651405883&partnerID=8YFLogxK

U2 - 10.1002/anie.201004876

DO - 10.1002/anie.201004876

M3 - Article

C2 - 21226164

AN - SCOPUS:78651405883

SN - 1433-7851

VL - 50

SP - 728

EP - 731

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 3

ER -

Photocatalytic production of hydrogen by disproportionation of one-electron-reduced rhodium and iridium-ruthenium complexes in water

Abstract

Keywords

Access to Document

Fingerprint

Cite this