Photo-isomerization effects on orientations of azobenzene-labeled polymer films measured by second harmonic generation

Byoungchoo Park, Hyoung Suk Kim, Joo Yun Bae, Jae Gyoung Lee, Hyung Suk Woo, S. H. Han, J. W. Wu, M. A. Kakimoto, H. Takezoe

Research output: Contribution to journalArticlepeer-review

Abstract

We have studied the changes in the orientational distribution functions of azobenzen-labeled polyamic acid monolayers before and after photoisomerization by measuring optical second-harmonic generation (SHG). From the surface SHG data, we determined the nonlinear-optical tensor components of the monolayers before and after the photo-isomerization. It is found that the point symmetry of the azo-pendant units in the monolayer changes from C∞υ to C by the photo-isomerization.

Original languageEnglish
Pages (from-to)291-294
Number of pages4
JournalMolecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume294-95
DOIs
StatePublished - 1997

Fingerprint

Dive into the research topics of 'Photo-isomerization effects on orientations of azobenzene-labeled polymer films measured by second harmonic generation'. Together they form a unique fingerprint.

Cite this