Abstract
We have studied the changes in the orientational distribution functions of azobenzen-labeled polyamic acid monolayers before and after photoisomerization by measuring optical second-harmonic generation (SHG). From the surface SHG data, we determined the nonlinear-optical tensor components of the monolayers before and after the photo-isomerization. It is found that the point symmetry of the azo-pendant units in the monolayer changes from C∞υ to C1υ by the photo-isomerization.
Original language | English |
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Pages (from-to) | 291-294 |
Number of pages | 4 |
Journal | Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals |
Volume | 294-95 |
DOIs | |
State | Published - 1997 |