Photo-cleavage of cobalt-carbon bonds of alkylcobalt(III) complexes by iodine with large quantum yields

Shunichi Fukuzumi; Tatsushi Goto; Kunio Ishikawa; Toshio Tanaka

doi:10.1039/C39890000260

Photo-cleavage of cobalt-carbon bonds of alkylcobalt(III) complexes by iodine with large quantum yields

Shunichi Fukuzumi
, Tatsushi Goto
, Kunio Ishikawa
, Toshio Tanaka

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Cobalt-carbon bonds of alkylcobalt(III) complexes are readily cleaved by iodine in carbon tetrachloride to yield alkyl iodides via photoinduced electron-transfer radical chain reactions with large quantum yields (e.g., Φ = 7.0 × 10³) under low energy irradiation (λ 509 nm).

Original language	English
Pages (from-to)	260-261
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	4
DOIs	https://doi.org/10.1039/C39890000260
State	Published - 1989

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@article{06c6bf29e22b4ca586ffcc4260dcef20,

title = "Photo-cleavage of cobalt-carbon bonds of alkylcobalt(III) complexes by iodine with large quantum yields",

abstract = "Cobalt-carbon bonds of alkylcobalt(III) complexes are readily cleaved by iodine in carbon tetrachloride to yield alkyl iodides via photoinduced electron-transfer radical chain reactions with large quantum yields (e.g., Φ = 7.0 × 103) under low energy irradiation (λ 509 nm).",

author = "Shunichi Fukuzumi and Tatsushi Goto and Kunio Ishikawa and Toshio Tanaka",

year = "1989",

doi = "10.1039/C39890000260",

language = "English",

pages = "260--261",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "4",

}

TY - JOUR

T1 - Photo-cleavage of cobalt-carbon bonds of alkylcobalt(III) complexes by iodine with large quantum yields

AU - Fukuzumi, Shunichi

AU - Goto, Tatsushi

AU - Ishikawa, Kunio

AU - Tanaka, Toshio

PY - 1989

Y1 - 1989

N2 - Cobalt-carbon bonds of alkylcobalt(III) complexes are readily cleaved by iodine in carbon tetrachloride to yield alkyl iodides via photoinduced electron-transfer radical chain reactions with large quantum yields (e.g., Φ = 7.0 × 103) under low energy irradiation (λ 509 nm).

AB - Cobalt-carbon bonds of alkylcobalt(III) complexes are readily cleaved by iodine in carbon tetrachloride to yield alkyl iodides via photoinduced electron-transfer radical chain reactions with large quantum yields (e.g., Φ = 7.0 × 103) under low energy irradiation (λ 509 nm).

UR - https://www.scopus.com/pages/publications/37049076202

U2 - 10.1039/C39890000260

DO - 10.1039/C39890000260

M3 - Article

AN - SCOPUS:37049076202

SN - 0022-4936

SP - 260

EP - 261

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 4

ER -

Photo-cleavage of cobalt-carbon bonds of alkylcobalt(III) complexes by iodine with large quantum yields

Abstract

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