(Pentaniethylcyclopentadienyl)ruthenium π-complexes of metalloporphyrins: Platforms with novel photo- And electrochemical properties

Luciano Cuesta; Elizabeth Karnas; Vincent M. Lynch; Jonathan L. Sessler; Wiroaj Kajonkijya; Weihua Zhu; Min Zhang; Zhongping Ou; Karl M. Kadish; Kei Ohkubo; Shunichi Fukuzumi

doi:10.1002/chem.200801748

(Pentaniethylcyclopentadienyl)ruthenium π-complexes of metalloporphyrins: Platforms with novel photo- And electrochemical properties

Luciano Cuesta
, Elizabeth Karnas
, Vincent M. Lynch
, Jonathan L. Sessler
, Wiroaj Kajonkijya
, Weihua Zhu
, Min Zhang
, Zhongping Ou
, Karl M. Kadish
, Kei Ohkubo
, Shunichi Fukuzumi

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

The hybrid metalloporphyrin-ruthenocene compounds were synthesized to investigate its photo- and electrochemical properties. The study used cyclic voltammetry, UV/Vis spectro-electrochemistry, ESR spectroscopy, and laser flash photolysis analysis to examine the photoinduced electron transfer from the ruthenocene moiety. It was observed during the study that the (pentamethylcyclopentadienyl)ruthenium π-complexes can be used as precursor to prepare multi-metallocene species. The study used elemental analysis, mass spectrometry, NMR, and ESR spectroscopies to investigate the properties of new bimetallic complexes. The study concluded that these ruthenocene metalloporphyrins can be used to develop new photovoltaic devices for various applications.

Original language	English
Pages (from-to)	10206-10210
Number of pages	5
Journal	Chemistry - A European Journal
Volume	14
Issue number	33
DOIs	https://doi.org/10.1002/chem.200801748
State	Published - 17 Nov 2008

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

Electrochemistry
Electronic communication
Photodynamics
Porphyrinoids
Ruthenocene

Access to Document

10.1002/chem.200801748

Cite this

Cuesta, L., Karnas, E., Lynch, V. M., Sessler, J. L., Kajonkijya, W., Zhu, W., Zhang, M., Ou, Z., Kadish, K. M., Ohkubo, K., & Fukuzumi, S. (2008). (Pentaniethylcyclopentadienyl)ruthenium π-complexes of metalloporphyrins: Platforms with novel photo- And electrochemical properties. Chemistry - A European Journal, 14(33), 10206-10210. https://doi.org/10.1002/chem.200801748

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title = "(Pentaniethylcyclopentadienyl)ruthenium π-complexes of metalloporphyrins: Platforms with novel photo- And electrochemical properties",

abstract = "The hybrid metalloporphyrin-ruthenocene compounds were synthesized to investigate its photo- and electrochemical properties. The study used cyclic voltammetry, UV/Vis spectro-electrochemistry, ESR spectroscopy, and laser flash photolysis analysis to examine the photoinduced electron transfer from the ruthenocene moiety. It was observed during the study that the (pentamethylcyclopentadienyl)ruthenium π-complexes can be used as precursor to prepare multi-metallocene species. The study used elemental analysis, mass spectrometry, NMR, and ESR spectroscopies to investigate the properties of new bimetallic complexes. The study concluded that these ruthenocene metalloporphyrins can be used to develop new photovoltaic devices for various applications.",

keywords = "Electrochemistry, Electronic communication, Photodynamics, Porphyrinoids, Ruthenocene",

author = "Luciano Cuesta and Elizabeth Karnas and Lynch, \{Vincent M.\} and Sessler, \{Jonathan L.\} and Wiroaj Kajonkijya and Weihua Zhu and Min Zhang and Zhongping Ou and Kadish, \{Karl M.\} and Kei Ohkubo and Shunichi Fukuzumi",

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T1 - (Pentaniethylcyclopentadienyl)ruthenium π-complexes of metalloporphyrins

T2 - Platforms with novel photo- And electrochemical properties

AU - Cuesta, Luciano

AU - Karnas, Elizabeth

AU - Lynch, Vincent M.

AU - Sessler, Jonathan L.

AU - Kajonkijya, Wiroaj

AU - Zhu, Weihua

AU - Zhang, Min

AU - Ou, Zhongping

AU - Kadish, Karl M.

AU - Ohkubo, Kei

AU - Fukuzumi, Shunichi

PY - 2008/11/17

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N2 - The hybrid metalloporphyrin-ruthenocene compounds were synthesized to investigate its photo- and electrochemical properties. The study used cyclic voltammetry, UV/Vis spectro-electrochemistry, ESR spectroscopy, and laser flash photolysis analysis to examine the photoinduced electron transfer from the ruthenocene moiety. It was observed during the study that the (pentamethylcyclopentadienyl)ruthenium π-complexes can be used as precursor to prepare multi-metallocene species. The study used elemental analysis, mass spectrometry, NMR, and ESR spectroscopies to investigate the properties of new bimetallic complexes. The study concluded that these ruthenocene metalloporphyrins can be used to develop new photovoltaic devices for various applications.

AB - The hybrid metalloporphyrin-ruthenocene compounds were synthesized to investigate its photo- and electrochemical properties. The study used cyclic voltammetry, UV/Vis spectro-electrochemistry, ESR spectroscopy, and laser flash photolysis analysis to examine the photoinduced electron transfer from the ruthenocene moiety. It was observed during the study that the (pentamethylcyclopentadienyl)ruthenium π-complexes can be used as precursor to prepare multi-metallocene species. The study used elemental analysis, mass spectrometry, NMR, and ESR spectroscopies to investigate the properties of new bimetallic complexes. The study concluded that these ruthenocene metalloporphyrins can be used to develop new photovoltaic devices for various applications.

KW - Electrochemistry

KW - Electronic communication

KW - Photodynamics

KW - Porphyrinoids

KW - Ruthenocene

UR - https://www.scopus.com/pages/publications/56349172626

U2 - 10.1002/chem.200801748

DO - 10.1002/chem.200801748

M3 - Article

AN - SCOPUS:56349172626

SN - 0947-6539

VL - 14

SP - 10206

EP - 10210

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 33

ER -

(Pentaniethylcyclopentadienyl)ruthenium π-complexes of metalloporphyrins: Platforms with novel photo- And electrochemical properties

Abstract

UN SDGs

Keywords

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