Pd(II) polymeric compounds directed by intermolecular C-H⋯X-C interactions (X = F, Cl): Suzuki-Miyaura cross-coupling catalytic activity by a novel N4-type saturated Pd complex

Jung Hwan Lee; Hee Jin Kim; Yun Wee Choi; Young Min Lee; Byeong Kwon Park; Cheal Kim; Sung Jin Kim; Youngmee Kim

doi:10.1016/j.poly.2006.11.020

Pd(II) polymeric compounds directed by intermolecular C-H⋯X-C interactions (X = F, Cl): Suzuki-Miyaura cross-coupling catalytic activity by a novel N4-type saturated Pd complex

Jung Hwan Lee, Hee Jin Kim, Yun Wee Choi, Young Min Lee, Byeong Kwon Park, Cheal Kim, Sung Jin Kim, Youngmee Kim

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

New palladium polymeric compounds containing novel tetradentate halogen-substituted 6Me₂bpX^2- ligands (6Me₂bpX^2- = 1,2-bis(6-methylpyridine-2-carboxamide) halobenzene dianion, X = F for 4, Cl for 5) were constructed by non-classical C-H⋯X-C interactions, and the novel catalyst 5 was used to carry out Suzuki coupling reactions with aryl iodides and aryl boronic acids under mild conditions.

Original language	English
Pages (from-to)	1388-1396
Number of pages	9
Journal	Polyhedron
Volume	26
Issue number	7
DOIs	https://doi.org/10.1016/j.poly.2006.11.020
State	Published - 1 May 2007

Bibliographical note

Funding Information:
Financial support from The SEOUL R & BD Program, the Korea Research Foundation (2002-070-C00053) and the Korean Science and Engineering Foundation (R01-2005-000-10490-0(2005) and ABRL R14-2003-014-01-001-0) is gratefully acknowledged.

Keywords

Crystal structures
Non-classical hydrogen bonds
Palladium(II) complexes
Suzuki-Miyaura cross-coupling

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10.1016/j.poly.2006.11.020

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title = "Pd(II) polymeric compounds directed by intermolecular C-H⋯X-C interactions (X = F, Cl): Suzuki-Miyaura cross-coupling catalytic activity by a novel N4-type saturated Pd complex",

abstract = "New palladium polymeric compounds containing novel tetradentate halogen-substituted 6Me2bpX2- ligands (6Me2bpX2- = 1,2-bis(6-methylpyridine-2-carboxamide) halobenzene dianion, X = F for 4, Cl for 5) were constructed by non-classical C-H⋯X-C interactions, and the novel catalyst 5 was used to carry out Suzuki coupling reactions with aryl iodides and aryl boronic acids under mild conditions.",

keywords = "Crystal structures, Non-classical hydrogen bonds, Palladium(II) complexes, Suzuki-Miyaura cross-coupling",

author = "Lee, {Jung Hwan} and Kim, {Hee Jin} and Choi, {Yun Wee} and Lee, {Young Min} and Park, {Byeong Kwon} and Cheal Kim and Kim, {Sung Jin} and Youngmee Kim",

note = "Funding Information: Financial support from The SEOUL R & BD Program, the Korea Research Foundation (2002-070-C00053) and the Korean Science and Engineering Foundation (R01-2005-000-10490-0(2005) and ABRL R14-2003-014-01-001-0) is gratefully acknowledged. ",

year = "2007",

month = may,

day = "1",

doi = "10.1016/j.poly.2006.11.020",

language = "English",

volume = "26",

pages = "1388--1396",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd.",

number = "7",

}

TY - JOUR

T1 - Pd(II) polymeric compounds directed by intermolecular C-H⋯X-C interactions (X = F, Cl)

T2 - Suzuki-Miyaura cross-coupling catalytic activity by a novel N4-type saturated Pd complex

AU - Lee, Jung Hwan

AU - Kim, Hee Jin

AU - Choi, Yun Wee

AU - Lee, Young Min

AU - Park, Byeong Kwon

AU - Kim, Cheal

AU - Kim, Sung Jin

AU - Kim, Youngmee

N1 - Funding Information: Financial support from The SEOUL R & BD Program, the Korea Research Foundation (2002-070-C00053) and the Korean Science and Engineering Foundation (R01-2005-000-10490-0(2005) and ABRL R14-2003-014-01-001-0) is gratefully acknowledged.

PY - 2007/5/1

Y1 - 2007/5/1

N2 - New palladium polymeric compounds containing novel tetradentate halogen-substituted 6Me2bpX2- ligands (6Me2bpX2- = 1,2-bis(6-methylpyridine-2-carboxamide) halobenzene dianion, X = F for 4, Cl for 5) were constructed by non-classical C-H⋯X-C interactions, and the novel catalyst 5 was used to carry out Suzuki coupling reactions with aryl iodides and aryl boronic acids under mild conditions.

AB - New palladium polymeric compounds containing novel tetradentate halogen-substituted 6Me2bpX2- ligands (6Me2bpX2- = 1,2-bis(6-methylpyridine-2-carboxamide) halobenzene dianion, X = F for 4, Cl for 5) were constructed by non-classical C-H⋯X-C interactions, and the novel catalyst 5 was used to carry out Suzuki coupling reactions with aryl iodides and aryl boronic acids under mild conditions.

KW - Crystal structures

KW - Non-classical hydrogen bonds

KW - Palladium(II) complexes

KW - Suzuki-Miyaura cross-coupling

UR - http://www.scopus.com/inward/record.url?scp=34147179972&partnerID=8YFLogxK

U2 - 10.1016/j.poly.2006.11.020

DO - 10.1016/j.poly.2006.11.020

M3 - Article

AN - SCOPUS:34147179972

SN - 0277-5387

VL - 26

SP - 1388

EP - 1396

JO - Polyhedron

JF - Polyhedron

IS - 7

ER -

Pd(II) polymeric compounds directed by intermolecular C-H⋯X-C interactions (X = F, Cl): Suzuki-Miyaura cross-coupling catalytic activity by a novel N4-type saturated Pd complex

Abstract

Bibliographical note

Keywords

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