Pd(II) polymeric compounds directed by intermolecular C-H⋯X-C interactions (X = F, Cl): Suzuki-Miyaura cross-coupling catalytic activity by a novel N4-type saturated Pd complex

Jung Hwan Lee, Hee Jin Kim, Yun Wee Choi, Young Min Lee, Byeong Kwon Park, Cheal Kim, Sung Jin Kim, Youngmee Kim

Research output: Contribution to journalArticlepeer-review

7 Scopus citations

Abstract

New palladium polymeric compounds containing novel tetradentate halogen-substituted 6Me2bpX2- ligands (6Me2bpX2- = 1,2-bis(6-methylpyridine-2-carboxamide) halobenzene dianion, X = F for 4, Cl for 5) were constructed by non-classical C-H⋯X-C interactions, and the novel catalyst 5 was used to carry out Suzuki coupling reactions with aryl iodides and aryl boronic acids under mild conditions.

Original languageEnglish
Pages (from-to)1388-1396
Number of pages9
JournalPolyhedron
Volume26
Issue number7
DOIs
StatePublished - 1 May 2007

Keywords

  • Crystal structures
  • Non-classical hydrogen bonds
  • Palladium(II) complexes
  • Suzuki-Miyaura cross-coupling

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