PbO2: From semi-metal to transparent conducting oxide by defect chemistry control

Aron Walsh; Aoife B. Kehoe; Douglas J. Temple; Graeme W. Watson; David O. Scanlon

doi:10.1039/c2cc35928f

PbO₂: From semi-metal to transparent conducting oxide by defect chemistry control

Aron Walsh
, Aoife B. Kehoe
, Douglas J. Temple
, Graeme W. Watson
, David O. Scanlon

Department of Physics

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

Lead dioxide has been studied for over 150 years as a component of the lead-acid battery. Based on first-principles calculations, we predict that by tuning the concentration of electrons in the material, through control of the defect chemistry, PbO₂ can be rendered from black to optically transparent, thus opening up applications in the field of optoelectronics.

Original language	English
Pages (from-to)	448-450
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	5
DOIs	https://doi.org/10.1039/c2cc35928f
State	Published - 11 Dec 2013

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title = "PbO2: From semi-metal to transparent conducting oxide by defect chemistry control",

abstract = "Lead dioxide has been studied for over 150 years as a component of the lead-acid battery. Based on first-principles calculations, we predict that by tuning the concentration of electrons in the material, through control of the defect chemistry, PbO2 can be rendered from black to optically transparent, thus opening up applications in the field of optoelectronics.",

author = "Aron Walsh and Kehoe, \{Aoife B.\} and Temple, \{Douglas J.\} and Watson, \{Graeme W.\} and Scanlon, \{David O.\}",

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doi = "10.1039/c2cc35928f",

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T2 - From semi-metal to transparent conducting oxide by defect chemistry control

AU - Walsh, Aron

AU - Kehoe, Aoife B.

AU - Temple, Douglas J.

AU - Watson, Graeme W.

AU - Scanlon, David O.

PY - 2013/12/11

Y1 - 2013/12/11

N2 - Lead dioxide has been studied for over 150 years as a component of the lead-acid battery. Based on first-principles calculations, we predict that by tuning the concentration of electrons in the material, through control of the defect chemistry, PbO2 can be rendered from black to optically transparent, thus opening up applications in the field of optoelectronics.

AB - Lead dioxide has been studied for over 150 years as a component of the lead-acid battery. Based on first-principles calculations, we predict that by tuning the concentration of electrons in the material, through control of the defect chemistry, PbO2 can be rendered from black to optically transparent, thus opening up applications in the field of optoelectronics.

UR - https://www.scopus.com/pages/publications/84871321657

U2 - 10.1039/c2cc35928f

DO - 10.1039/c2cc35928f

M3 - Article

AN - SCOPUS:84871321657

SN - 1359-7345

VL - 49

SP - 448

EP - 450

JO - Chemical Communications

JF - Chemical Communications

IS - 5

ER -

PbO2: From semi-metal to transparent conducting oxide by defect chemistry control

Abstract

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PbO₂: From semi-metal to transparent conducting oxide by defect chemistry control