Oxygen-atom transfer between mononuclear nonheme iron(IV)-oxo and iron(II) complexes

Chivukula V. Sastri, Kyungeun Oh, Yoon Jin Lee, Mi Sook Seo, Woonsup Shin, Wonwoo Nam

Research output: Contribution to journalArticlepeer-review

56 Scopus citations

Abstract

(Figure Presented) Completing the move: The intermetal transfer of an oxygen atom from nonheme iron(IV)-oxo to iron(II) complexes (see example, purple: Fe, red: O, blue: N, gray: C) has been unambiguously evidenced spectrophotometrically, mass spectrometrically, and electrochemically. The transfer of the oxygen atom was found to be dependent on the oxidizing power of the iron(IV)-oxo complexes.

Original languageEnglish
Pages (from-to)3992-3995
Number of pages4
JournalAngewandte Chemie - International Edition
Volume45
Issue number24
DOIs
StatePublished - 12 Jun 2006

Keywords

  • Coordination modes
  • Enzyme models
  • Iron
  • N ligands
  • Oxygen

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