Oxygen-atom transfer between mononuclear nonheme iron(IV)-oxo and iron(II) complexes

Chivukula V. Sastri; Kyungeun Oh; Yoon Jin Lee; Mi Sook Seo; Woonsup Shin; Wonwoo Nam

doi:10.1002/anie.200504422

Oxygen-atom transfer between mononuclear nonheme iron(IV)-oxo and iron(II) complexes

Chivukula V. Sastri, Kyungeun Oh, Yoon Jin Lee, Mi Sook Seo, Woonsup Shin, Wonwoo Nam

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

58 Scopus citations

Abstract

(Figure Presented) Completing the move: The intermetal transfer of an oxygen atom from nonheme iron(IV)-oxo to iron(II) complexes (see example, purple: Fe, red: O, blue: N, gray: C) has been unambiguously evidenced spectrophotometrically, mass spectrometrically, and electrochemically. The transfer of the oxygen atom was found to be dependent on the oxidizing power of the iron(IV)-oxo complexes.

Original language	English
Pages (from-to)	3992-3995
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	45
Issue number	24
DOIs	https://doi.org/10.1002/anie.200504422
State	Published - 12 Jun 2006

Keywords

Coordination modes
Enzyme models
Iron
N ligands
Oxygen

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title = "Oxygen-atom transfer between mononuclear nonheme iron(IV)-oxo and iron(II) complexes",

abstract = "(Figure Presented) Completing the move: The intermetal transfer of an oxygen atom from nonheme iron(IV)-oxo to iron(II) complexes (see example, purple: Fe, red: O, blue: N, gray: C) has been unambiguously evidenced spectrophotometrically, mass spectrometrically, and electrochemically. The transfer of the oxygen atom was found to be dependent on the oxidizing power of the iron(IV)-oxo complexes.",

keywords = "Coordination modes, Enzyme models, Iron, N ligands, Oxygen",

author = "Sastri, {Chivukula V.} and Kyungeun Oh and Lee, {Yoon Jin} and Seo, {Mi Sook} and Woonsup Shin and Wonwoo Nam",

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T1 - Oxygen-atom transfer between mononuclear nonheme iron(IV)-oxo and iron(II) complexes

AU - Sastri, Chivukula V.

AU - Oh, Kyungeun

AU - Lee, Yoon Jin

AU - Seo, Mi Sook

AU - Shin, Woonsup

AU - Nam, Wonwoo

PY - 2006/6/12

Y1 - 2006/6/12

N2 - (Figure Presented) Completing the move: The intermetal transfer of an oxygen atom from nonheme iron(IV)-oxo to iron(II) complexes (see example, purple: Fe, red: O, blue: N, gray: C) has been unambiguously evidenced spectrophotometrically, mass spectrometrically, and electrochemically. The transfer of the oxygen atom was found to be dependent on the oxidizing power of the iron(IV)-oxo complexes.

AB - (Figure Presented) Completing the move: The intermetal transfer of an oxygen atom from nonheme iron(IV)-oxo to iron(II) complexes (see example, purple: Fe, red: O, blue: N, gray: C) has been unambiguously evidenced spectrophotometrically, mass spectrometrically, and electrochemically. The transfer of the oxygen atom was found to be dependent on the oxidizing power of the iron(IV)-oxo complexes.

KW - Coordination modes

KW - Enzyme models

KW - Iron

KW - N ligands

KW - Oxygen

UR - http://www.scopus.com/inward/record.url?scp=33746287535&partnerID=8YFLogxK

U2 - 10.1002/anie.200504422

DO - 10.1002/anie.200504422

M3 - Article

C2 - 16688689

AN - SCOPUS:33746287535

SN - 1433-7851

VL - 45

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EP - 3995

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 24

ER -

Oxygen-atom transfer between mononuclear nonheme iron(IV)-oxo and iron(II) complexes

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Keywords

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