Oxidative properties of a nonheme Ni(ii)(O2) complex: Reactivity patterns for C-H activation, aromatic hydroxylation and heteroatom oxidation

Reza Latifi; Laleh Tahsini; Devesh Kumar; G. Narahari Sastry; Wonwoo Nam; Sam P. De Visser

doi:10.1039/c1cc13993b

Oxidative properties of a nonheme Ni(ii)(O₂) complex: Reactivity patterns for C-H activation, aromatic hydroxylation and heteroatom oxidation

Reza Latifi
, Laleh Tahsini
, Devesh Kumar
, G. Narahari Sastry
, Wonwoo Nam
, Sam P. De Visser

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

Density functional theory calculations on the reactivity of a Ni(ii)-superoxo complex in C-H bond activation, aromatic hydroxylation and heteroatom oxidation reactions have been explored; the Ni(ii)-superoxo complex is able to react with substrates with weak C-H bonds and PPh₃.

Original language	English
Pages (from-to)	10674-10676
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	38
DOIs	https://doi.org/10.1039/c1cc13993b
State	Published - 14 Oct 2011

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title = "Oxidative properties of a nonheme Ni(ii)(O2) complex: Reactivity patterns for C-H activation, aromatic hydroxylation and heteroatom oxidation",

abstract = "Density functional theory calculations on the reactivity of a Ni(ii)-superoxo complex in C-H bond activation, aromatic hydroxylation and heteroatom oxidation reactions have been explored; the Ni(ii)-superoxo complex is able to react with substrates with weak C-H bonds and PPh3.",

author = "Reza Latifi and Laleh Tahsini and Devesh Kumar and Sastry, \{G. Narahari\} and Wonwoo Nam and \{De Visser\}, \{Sam P.\}",

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journal = "Chemical Communications",

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AU - Latifi, Reza

AU - Tahsini, Laleh

AU - Kumar, Devesh

AU - Sastry, G. Narahari

AU - Nam, Wonwoo

AU - De Visser, Sam P.

PY - 2011/10/14

Y1 - 2011/10/14

N2 - Density functional theory calculations on the reactivity of a Ni(ii)-superoxo complex in C-H bond activation, aromatic hydroxylation and heteroatom oxidation reactions have been explored; the Ni(ii)-superoxo complex is able to react with substrates with weak C-H bonds and PPh3.

AB - Density functional theory calculations on the reactivity of a Ni(ii)-superoxo complex in C-H bond activation, aromatic hydroxylation and heteroatom oxidation reactions have been explored; the Ni(ii)-superoxo complex is able to react with substrates with weak C-H bonds and PPh3.

UR - https://www.scopus.com/pages/publications/80052946740

U2 - 10.1039/c1cc13993b

DO - 10.1039/c1cc13993b

M3 - Article

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AN - SCOPUS:80052946740

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VL - 47

SP - 10674

EP - 10676

JO - Chemical Communications

JF - Chemical Communications

IS - 38

ER -

Oxidative properties of a nonheme Ni(ii)(O2) complex: Reactivity patterns for C-H activation, aromatic hydroxylation and heteroatom oxidation

Abstract

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Oxidative properties of a nonheme Ni(ii)(O₂) complex: Reactivity patterns for C-H activation, aromatic hydroxylation and heteroatom oxidation