Oxidative properties of a nonheme Ni(ii)(O2) complex: Reactivity patterns for C-H activation, aromatic hydroxylation and heteroatom oxidation

Reza Latifi, Laleh Tahsini, Devesh Kumar, G. Narahari Sastry, Wonwoo Nam, Sam P. De Visser

Research output: Contribution to journalArticlepeer-review

22 Scopus citations

Abstract

Density functional theory calculations on the reactivity of a Ni(ii)-superoxo complex in C-H bond activation, aromatic hydroxylation and heteroatom oxidation reactions have been explored; the Ni(ii)-superoxo complex is able to react with substrates with weak C-H bonds and PPh3.

Original languageEnglish
Pages (from-to)10674-10676
Number of pages3
JournalChemical Communications
Volume47
Issue number38
DOIs
StatePublished - 14 Oct 2011

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