Oxidation mechanism of NAD dimer model compounds

Matthias Patz; Yoshihiro Kuwahara; Tomoyoshi Suenobu; Shunichi Fukuzumi

doi:10.1246/cl.1997.567

Oxidation mechanism of NAD dimer model compounds

Matthias Patz, Yoshihiro Kuwahara, Tomoyoshi Suenobu, Shunichi Fukuzumi

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

57 Scopus citations

Abstract

The oxidation of a dimeric N-benzyldihydronicotinamide with various oxidants such as quinones, triphenyl carbenium ions and a triplet exited tris(bipyridine) ruthenium(II) complex occurs via initial outer-sphere electron transfer followed by fast C-C bond cleavage and second electron transfer. The kinetic studies allow the determination of the oxidation potential of this compound.

Original language	English
Pages (from-to)	567-568
Number of pages	2
Journal	Chemistry Letters
Issue number	6
DOIs	https://doi.org/10.1246/cl.1997.567
State	Published - 1997

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title = "Oxidation mechanism of NAD dimer model compounds",

abstract = "The oxidation of a dimeric N-benzyldihydronicotinamide with various oxidants such as quinones, triphenyl carbenium ions and a triplet exited tris(bipyridine) ruthenium(II) complex occurs via initial outer-sphere electron transfer followed by fast C-C bond cleavage and second electron transfer. The kinetic studies allow the determination of the oxidation potential of this compound.",

author = "Matthias Patz and Yoshihiro Kuwahara and Tomoyoshi Suenobu and Shunichi Fukuzumi",

year = "1997",

doi = "10.1246/cl.1997.567",

language = "English",

pages = "567--568",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "The Chemical Society of Japan",

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T1 - Oxidation mechanism of NAD dimer model compounds

AU - Patz, Matthias

AU - Kuwahara, Yoshihiro

AU - Suenobu, Tomoyoshi

AU - Fukuzumi, Shunichi

PY - 1997

Y1 - 1997

N2 - The oxidation of a dimeric N-benzyldihydronicotinamide with various oxidants such as quinones, triphenyl carbenium ions and a triplet exited tris(bipyridine) ruthenium(II) complex occurs via initial outer-sphere electron transfer followed by fast C-C bond cleavage and second electron transfer. The kinetic studies allow the determination of the oxidation potential of this compound.

AB - The oxidation of a dimeric N-benzyldihydronicotinamide with various oxidants such as quinones, triphenyl carbenium ions and a triplet exited tris(bipyridine) ruthenium(II) complex occurs via initial outer-sphere electron transfer followed by fast C-C bond cleavage and second electron transfer. The kinetic studies allow the determination of the oxidation potential of this compound.

UR - http://www.scopus.com/inward/record.url?scp=0031521116&partnerID=8YFLogxK

U2 - 10.1246/cl.1997.567

DO - 10.1246/cl.1997.567

M3 - Article

AN - SCOPUS:0031521116

SN - 0366-7022

SP - 567

EP - 568

JO - Chemistry Letters

JF - Chemistry Letters

IS - 6

ER -

Oxidation mechanism of NAD dimer model compounds

Abstract

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