Abstract
(Chemical Equation Presented) ARC de triomphe: Ortho-TMS benzaldehyde permits efficient multicomponent union of a variety of nucleophiles and electrophiles, including the first example of a Pd-mediated ARC Type II process. A "proof-of-concept" synthetic sequence was designed and implemented for construction of a focused library of "natural product-like" compounds (see scheme). ARC: anion relay chemistry.
Original language | English |
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Pages (from-to) | 7082-7086 |
Number of pages | 5 |
Journal | Angewandte Chemie - International Edition |
Volume | 47 |
Issue number | 37 |
DOIs | |
State | Published - 1 Sep 2008 |
Keywords
- Anion relay chemistry
- Cross-coupling
- Dithianes
- Molecular diversity
- Natural products