One-step formation of functionalized block copolymers

Didier Benoit; Craig J. Hawker; Elbert E. Huang; Zhiqun Lin; Thomas P. Russell

doi:10.1021/ma991721p

One-step formation of functionalized block copolymers

Didier Benoit, Craig J. Hawker, Elbert E. Huang, Zhiqun Lin, Thomas P. Russell

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

206 Scopus citations

Abstract

In this study, living free radical procedures are extended to reactive monomers such as maleic anhydride, by the use of a mixture of α-hydrido alkoxyamine, and nitroxide. In copolymerizations with styrene, the living nature of the polymerization is preserved, which leads to preferential consumption of functionalized block copolymers, whose molecular weights can be readily controlled up to 100000 while retaining low polydispersities.

Original language	English
Pages (from-to)	1505-1507
Number of pages	3
Journal	Macromolecules
Volume	33
Issue number	5
DOIs	https://doi.org/10.1021/ma991721p
State	Published - 7 Mar 2000

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title = "One-step formation of functionalized block copolymers",

abstract = "In this study, living free radical procedures are extended to reactive monomers such as maleic anhydride, by the use of a mixture of α-hydrido alkoxyamine, and nitroxide. In copolymerizations with styrene, the living nature of the polymerization is preserved, which leads to preferential consumption of functionalized block copolymers, whose molecular weights can be readily controlled up to 100000 while retaining low polydispersities.",

author = "Didier Benoit and Hawker, {Craig J.} and Huang, {Elbert E.} and Zhiqun Lin and Russell, {Thomas P.}",

year = "2000",

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T1 - One-step formation of functionalized block copolymers

AU - Benoit, Didier

AU - Hawker, Craig J.

AU - Huang, Elbert E.

AU - Lin, Zhiqun

AU - Russell, Thomas P.

PY - 2000/3/7

Y1 - 2000/3/7

N2 - In this study, living free radical procedures are extended to reactive monomers such as maleic anhydride, by the use of a mixture of α-hydrido alkoxyamine, and nitroxide. In copolymerizations with styrene, the living nature of the polymerization is preserved, which leads to preferential consumption of functionalized block copolymers, whose molecular weights can be readily controlled up to 100000 while retaining low polydispersities.

AB - In this study, living free radical procedures are extended to reactive monomers such as maleic anhydride, by the use of a mixture of α-hydrido alkoxyamine, and nitroxide. In copolymerizations with styrene, the living nature of the polymerization is preserved, which leads to preferential consumption of functionalized block copolymers, whose molecular weights can be readily controlled up to 100000 while retaining low polydispersities.

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DO - 10.1021/ma991721p

M3 - Article

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VL - 33

SP - 1505

EP - 1507

JO - Macromolecules

JF - Macromolecules

IS - 5

ER -

One-step formation of functionalized block copolymers

Abstract

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