One-pot synthesis of platinum nanoparticles embedded on reduced graphene oxide for oxygen reduction in methanol fuel cells

Hyung Wook Ha; In Young Kim; Seong Ju Hwang; Rodney S. Ruoff

doi:10.1149/1.3584092

One-pot synthesis of platinum nanoparticles embedded on reduced graphene oxide for oxygen reduction in methanol fuel cells

Hyung Wook Ha, In Young Kim, Seong Ju Hwang, Rodney S. Ruoff

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

91 Scopus citations

Abstract

A simple approach has been developed for the synthesis of Pt nanoparticles with uniform diameters of approximately 2.9 nm supported on reduced graphene oxide (RG-O) platelets via a modified polyol method. Compared to Johnson Matthey (JM) Pt/C (75 wt Pt) catalyst, the Pt/RG-O (70 wt Pt) composite showed much higher electrochemical surface area, greater catalytic activity towards the oxygen reduction reaction (ORR), and significantly better single cell polarization performance. The maximum power density of the Pt/RG-O composite was about 128 mW cm^-2, an 11 greater than the JM Pt/C commercial catalyst.

Original language	English
Pages (from-to)	B70-B73
Journal	Electrochemical and Solid-State Letters
Volume	14
Issue number	7
DOIs	https://doi.org/10.1149/1.3584092
State	Published - 2011

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title = "One-pot synthesis of platinum nanoparticles embedded on reduced graphene oxide for oxygen reduction in methanol fuel cells",

abstract = "A simple approach has been developed for the synthesis of Pt nanoparticles with uniform diameters of approximately 2.9 nm supported on reduced graphene oxide (RG-O) platelets via a modified polyol method. Compared to Johnson Matthey (JM) Pt/C (75 wt Pt) catalyst, the Pt/RG-O (70 wt Pt) composite showed much higher electrochemical surface area, greater catalytic activity towards the oxygen reduction reaction (ORR), and significantly better single cell polarization performance. The maximum power density of the Pt/RG-O composite was about 128 mW cm-2, an 11 greater than the JM Pt/C commercial catalyst.",

author = "Ha, \{Hyung Wook\} and Kim, \{In Young\} and Hwang, \{Seong Ju\} and Ruoff, \{Rodney S.\}",

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AU - Ha, Hyung Wook

AU - Kim, In Young

AU - Hwang, Seong Ju

AU - Ruoff, Rodney S.

PY - 2011

Y1 - 2011

N2 - A simple approach has been developed for the synthesis of Pt nanoparticles with uniform diameters of approximately 2.9 nm supported on reduced graphene oxide (RG-O) platelets via a modified polyol method. Compared to Johnson Matthey (JM) Pt/C (75 wt Pt) catalyst, the Pt/RG-O (70 wt Pt) composite showed much higher electrochemical surface area, greater catalytic activity towards the oxygen reduction reaction (ORR), and significantly better single cell polarization performance. The maximum power density of the Pt/RG-O composite was about 128 mW cm-2, an 11 greater than the JM Pt/C commercial catalyst.

AB - A simple approach has been developed for the synthesis of Pt nanoparticles with uniform diameters of approximately 2.9 nm supported on reduced graphene oxide (RG-O) platelets via a modified polyol method. Compared to Johnson Matthey (JM) Pt/C (75 wt Pt) catalyst, the Pt/RG-O (70 wt Pt) composite showed much higher electrochemical surface area, greater catalytic activity towards the oxygen reduction reaction (ORR), and significantly better single cell polarization performance. The maximum power density of the Pt/RG-O composite was about 128 mW cm-2, an 11 greater than the JM Pt/C commercial catalyst.

UR - https://www.scopus.com/pages/publications/79959548848

U2 - 10.1149/1.3584092

DO - 10.1149/1.3584092

M3 - Article

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VL - 14

SP - B70-B73

JO - Electrochemical and Solid-State Letters

JF - Electrochemical and Solid-State Letters

IS - 7

ER -

One-pot synthesis of platinum nanoparticles embedded on reduced graphene oxide for oxygen reduction in methanol fuel cells

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