Octahedral hexahydroxo rhenium cluster complexes [Re6Q 8(OH)6]4-.(Q = S, Se): Synthesis, structure, and properties

Spartak S. Yarovoi; Yuri V. Mironov; Dmitry Y. Naumov; Yuri V. Gatilov; Svetlana G. Kozlova; Sung Jin Kim; Vladimir E. Fedorov

doi:10.1002/ejic.200500284

Octahedral hexahydroxo rhenium cluster complexes [Re₆Q ₈(OH)₆]^4-.(Q = S, Se): Synthesis, structure, and properties

Spartak S. Yarovoi, Yuri V. Mironov, Dmitry Y. Naumov, Yuri V. Gatilov, Svetlana G. Kozlova, Sung Jin Kim, Vladimir E. Fedorov

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

97 Scopus citations

Abstract

Two novel rhenium cluster compounds, K₄[Re₆S ₈(OH)₆]·8H₂O (1) and K ₄[Re₆Se₈(OH)₆]·8H ₂O (2), containing octahedral cluster chalcogenide anionic complexes [Re₆Q₈(OH)₆]^4- with terminal hydroxo ligands have been synthesized by the reaction of Re₆Q ₈Br₂ (Q = S, Se) with molten KOH. Two chalcohalide compounds, one known (Cs₄[Re₆S₈Br ₆]·2H₂O, 3) and another new (Cs₃[Re ₆Se₈Cl₆]·2H₂O, 4), were prepared by reactions of 1 and 2 with CsX and HX (X = Br, Cl) in an aqueous solution. Compounds 1, 2, and 4 have been characterized by the single-crystal X-ray diffraction method. Compounds 1 and 2 are crystallized in triclinic space group P1 with one formula unit in the cell of dimensions a = 8.4936(8) Å, b = 8.9101(11) Å, c = 10.5940(13) Å, α = 77.935(11)°, β = 75.933(9)°, γ = 71.244(10)°, V = 728.9(1) Å³ (compound 1) and a = 8.613(1) Å, b = 8.996(1) Å, c = 10.057(1) Å, α = 78.587(2)°, β = 77.811(2)°, γ = 71.728(2)°, V = 715.9(2) Å³ (compound 2). Compound 4 crystallizes in the monoclinic space group P2₁/n with two formula units in the cell of dimensions a = 9.819(3) Å, b = 12.925(4) Å, c = 11.756(4) Å, β = 113.38(3)°, V = 1369.6(8) Å³. Compounds 1 and 2 display luminescent properties.

Original language	English
Pages (from-to)	3945-3949
Number of pages	5
Journal	European Journal of Inorganic Chemistry
Issue number	19
DOIs	https://doi.org/10.1002/ejic.200500284
State	Published - 7 Oct 2005

Bibliographical note

Funding Information:
We would like to thank Michigan State University’s High-Performance Computing Cluster and the University of Auckland for providing computing resources. This study was funded by the National Institute of Arthritis and Musculoskeletal and Skin Diseases P50AR060772 (Insight CORT), and by Michigan State University. JOS and TF were funded by the Dines Family Charitable Trust and a Health Research Council Explorer Grant (HRC 19/774).

Funding Information:
This study was funded by the National Institute of Arthritis and Musculoskeletal and Skin Diseases P50AR060772 (Insight CORT), and by Michigan State University. JOS and TF were funded by the Dines Family Charitable Trust and a Health Research Council Explorer Grant (HRC 19/774).

Keywords

Cluster compounds
Electronic structure
Hexahydroxo complexes
Luminescence
Rhenium

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10.1002/ejic.200500284

Cite this

@article{79783f61bcf54d5686ef5d10313005a2,

title = "Octahedral hexahydroxo rhenium cluster complexes [Re6Q 8(OH)6]4-.(Q = S, Se): Synthesis, structure, and properties",

abstract = "Two novel rhenium cluster compounds, K4[Re6S 8(OH)6]·8H2O (1) and K 4[Re6Se8(OH)6]·8H 2O (2), containing octahedral cluster chalcogenide anionic complexes [Re6Q8(OH)6]4- with terminal hydroxo ligands have been synthesized by the reaction of Re6Q 8Br2 (Q = S, Se) with molten KOH. Two chalcohalide compounds, one known (Cs4[Re6S8Br 6]·2H2O, 3) and another new (Cs3[Re 6Se8Cl6]·2H2O, 4), were prepared by reactions of 1 and 2 with CsX and HX (X = Br, Cl) in an aqueous solution. Compounds 1, 2, and 4 have been characterized by the single-crystal X-ray diffraction method. Compounds 1 and 2 are crystallized in triclinic space group P1 with one formula unit in the cell of dimensions a = 8.4936(8) {\AA}, b = 8.9101(11) {\AA}, c = 10.5940(13) {\AA}, α = 77.935(11)°, β = 75.933(9)°, γ = 71.244(10)°, V = 728.9(1) {\AA}3 (compound 1) and a = 8.613(1) {\AA}, b = 8.996(1) {\AA}, c = 10.057(1) {\AA}, α = 78.587(2)°, β = 77.811(2)°, γ = 71.728(2)°, V = 715.9(2) {\AA}3 (compound 2). Compound 4 crystallizes in the monoclinic space group P21/n with two formula units in the cell of dimensions a = 9.819(3) {\AA}, b = 12.925(4) {\AA}, c = 11.756(4) {\AA}, β = 113.38(3)°, V = 1369.6(8) {\AA}3. Compounds 1 and 2 display luminescent properties.",

keywords = "Cluster compounds, Electronic structure, Hexahydroxo complexes, Luminescence, Rhenium",

author = "Yarovoi, {Spartak S.} and Mironov, {Yuri V.} and Naumov, {Dmitry Y.} and Gatilov, {Yuri V.} and Kozlova, {Svetlana G.} and Kim, {Sung Jin} and Fedorov, {Vladimir E.}",

note = "Funding Information: We would like to thank Michigan State University{\textquoteright}s High-Performance Computing Cluster and the University of Auckland for providing computing resources. This study was funded by the National Institute of Arthritis and Musculoskeletal and Skin Diseases P50AR060772 (Insight CORT), and by Michigan State University. JOS and TF were funded by the Dines Family Charitable Trust and a Health Research Council Explorer Grant (HRC 19/774). Funding Information: This study was funded by the National Institute of Arthritis and Musculoskeletal and Skin Diseases P50AR060772 (Insight CORT), and by Michigan State University. JOS and TF were funded by the Dines Family Charitable Trust and a Health Research Council Explorer Grant (HRC 19/774).",

year = "2005",

month = oct,

day = "7",

doi = "10.1002/ejic.200500284",

language = "English",

pages = "3945--3949",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

publisher = "Wiley-VCH Verlag",

number = "19",

}

TY - JOUR

T1 - Octahedral hexahydroxo rhenium cluster complexes [Re6Q 8(OH)6]4-.(Q = S, Se)

T2 - Synthesis, structure, and properties

AU - Yarovoi, Spartak S.

AU - Mironov, Yuri V.

AU - Naumov, Dmitry Y.

AU - Gatilov, Yuri V.

AU - Kozlova, Svetlana G.

AU - Kim, Sung Jin

AU - Fedorov, Vladimir E.

N1 - Funding Information: We would like to thank Michigan State University’s High-Performance Computing Cluster and the University of Auckland for providing computing resources. This study was funded by the National Institute of Arthritis and Musculoskeletal and Skin Diseases P50AR060772 (Insight CORT), and by Michigan State University. JOS and TF were funded by the Dines Family Charitable Trust and a Health Research Council Explorer Grant (HRC 19/774). Funding Information: This study was funded by the National Institute of Arthritis and Musculoskeletal and Skin Diseases P50AR060772 (Insight CORT), and by Michigan State University. JOS and TF were funded by the Dines Family Charitable Trust and a Health Research Council Explorer Grant (HRC 19/774).

PY - 2005/10/7

Y1 - 2005/10/7

N2 - Two novel rhenium cluster compounds, K4[Re6S 8(OH)6]·8H2O (1) and K 4[Re6Se8(OH)6]·8H 2O (2), containing octahedral cluster chalcogenide anionic complexes [Re6Q8(OH)6]4- with terminal hydroxo ligands have been synthesized by the reaction of Re6Q 8Br2 (Q = S, Se) with molten KOH. Two chalcohalide compounds, one known (Cs4[Re6S8Br 6]·2H2O, 3) and another new (Cs3[Re 6Se8Cl6]·2H2O, 4), were prepared by reactions of 1 and 2 with CsX and HX (X = Br, Cl) in an aqueous solution. Compounds 1, 2, and 4 have been characterized by the single-crystal X-ray diffraction method. Compounds 1 and 2 are crystallized in triclinic space group P1 with one formula unit in the cell of dimensions a = 8.4936(8) Å, b = 8.9101(11) Å, c = 10.5940(13) Å, α = 77.935(11)°, β = 75.933(9)°, γ = 71.244(10)°, V = 728.9(1) Å3 (compound 1) and a = 8.613(1) Å, b = 8.996(1) Å, c = 10.057(1) Å, α = 78.587(2)°, β = 77.811(2)°, γ = 71.728(2)°, V = 715.9(2) Å3 (compound 2). Compound 4 crystallizes in the monoclinic space group P21/n with two formula units in the cell of dimensions a = 9.819(3) Å, b = 12.925(4) Å, c = 11.756(4) Å, β = 113.38(3)°, V = 1369.6(8) Å3. Compounds 1 and 2 display luminescent properties.

AB - Two novel rhenium cluster compounds, K4[Re6S 8(OH)6]·8H2O (1) and K 4[Re6Se8(OH)6]·8H 2O (2), containing octahedral cluster chalcogenide anionic complexes [Re6Q8(OH)6]4- with terminal hydroxo ligands have been synthesized by the reaction of Re6Q 8Br2 (Q = S, Se) with molten KOH. Two chalcohalide compounds, one known (Cs4[Re6S8Br 6]·2H2O, 3) and another new (Cs3[Re 6Se8Cl6]·2H2O, 4), were prepared by reactions of 1 and 2 with CsX and HX (X = Br, Cl) in an aqueous solution. Compounds 1, 2, and 4 have been characterized by the single-crystal X-ray diffraction method. Compounds 1 and 2 are crystallized in triclinic space group P1 with one formula unit in the cell of dimensions a = 8.4936(8) Å, b = 8.9101(11) Å, c = 10.5940(13) Å, α = 77.935(11)°, β = 75.933(9)°, γ = 71.244(10)°, V = 728.9(1) Å3 (compound 1) and a = 8.613(1) Å, b = 8.996(1) Å, c = 10.057(1) Å, α = 78.587(2)°, β = 77.811(2)°, γ = 71.728(2)°, V = 715.9(2) Å3 (compound 2). Compound 4 crystallizes in the monoclinic space group P21/n with two formula units in the cell of dimensions a = 9.819(3) Å, b = 12.925(4) Å, c = 11.756(4) Å, β = 113.38(3)°, V = 1369.6(8) Å3. Compounds 1 and 2 display luminescent properties.

KW - Cluster compounds

KW - Electronic structure

KW - Hexahydroxo complexes

KW - Luminescence

KW - Rhenium

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U2 - 10.1002/ejic.200500284

DO - 10.1002/ejic.200500284

M3 - Article

AN - SCOPUS:29744443296

SN - 1434-1948

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JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

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