TY - JOUR
T1 - Observation of highly excited electronic states of (CO2)m clusters
AU - Campbell, E. E.B.
AU - Tittes, A.
N1 - Funding Information:
The authors would like to thank Professor I.V. Hertel for his continuous interest in the present work. This work has been financially supported by the Deutsche Forschungsgemeinschaft through Sonder-forschungsbereich 337 in Berlin, “Energy and Charge Transfer in Molecular Aggregates”.
PY - 1990/1/19
Y1 - 1990/1/19
N2 - Highly excited, Rydberg states of carbon dioxide clusters have been produced in a "Lineberger-type" cluster source and detected via field ionisation. Lifetimes of these states have been shown to be greater than 50 μs for principal quantum numbers 50≤n≤75. As the cluster size increases there appears to be a greater contribution to the signal from species with lower field ionisation rates.
AB - Highly excited, Rydberg states of carbon dioxide clusters have been produced in a "Lineberger-type" cluster source and detected via field ionisation. Lifetimes of these states have been shown to be greater than 50 μs for principal quantum numbers 50≤n≤75. As the cluster size increases there appears to be a greater contribution to the signal from species with lower field ionisation rates.
UR - http://www.scopus.com/inward/record.url?scp=0041144978&partnerID=8YFLogxK
U2 - 10.1016/0009-2614(90)87190-3
DO - 10.1016/0009-2614(90)87190-3
M3 - Article
AN - SCOPUS:0041144978
VL - 165
SP - 289
EP - 292
JO - Chemical Physics Letters
JF - Chemical Physics Letters
SN - 0009-2614
IS - 4
ER -