Novel three-dimensional coordination polymers based on [Mo 6Se8(CN)6]7- anions and Mn 2+ Cations

Konstantin A. Brylev, Nikolay G. Naumov, Alexander V. Virovets, Sung Jin Kim, Vladimir E. Fedorov

Research output: Contribution to journalArticlepeer-review

18 Scopus citations

Abstract

Three novel coordination polymers K5[MnMo6Se 8(CN)6] • 8H2O (1), (Me4N) 4[{Mn(H2O)2}1.5Mo6Se 8(CN)6] • 4H2O (2), and K 3[{Mn2(H2O)4}Mo6Se 8(CN)6] • 7H2O (3) have been synthesized by layering of a methanol solution of [Mn(salen)]CH3COO (salen-N,N′-bis(salicylidene)ethylenediamine) on an aqueous solution of K7[Mo6Se8(CN)6] • 8H 2O. The compounds have been characterized by single-crystal X-ray diffraction analysis. All structures are based on negatively charged porous polymer frameworks where CN groups of [Mo6Se8(CN) 6]7- cluster complexes are coordinated to Mn2+ cations. Cavities in the frameworks are filled by additional cations and solvate water molecules.

Original languageEnglish
Pages (from-to)165-176
Number of pages12
JournalJournal of Cluster Science
Volume20
Issue number1
DOIs
StatePublished - Mar 2009

Keywords

  • Cluster Compounds
  • Crystal structure
  • Cyanides
  • Molybdenum

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