Novel three-dimensional coordination polymers based on [Mo 6Se8(CN)6]7- anions and Mn 2+ Cations

Konstantin A. Brylev; Nikolay G. Naumov; Alexander V. Virovets; Sung Jin Kim; Vladimir E. Fedorov

doi:10.1007/s10876-008-0215-4

Novel three-dimensional coordination polymers based on [Mo ₆Se₈(CN)₆]^7- anions and Mn ²⁺ Cations

Konstantin A. Brylev, Nikolay G. Naumov, Alexander V. Virovets, Sung Jin Kim, Vladimir E. Fedorov

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

Three novel coordination polymers K₅[MnMo₆Se ₈(CN)₆] • 8H₂O (1), (Me₄N) ₄[{Mn(H₂O)₂}_1.5Mo₆Se ₈(CN)₆] • 4H₂O (2), and K ₃[{Mn₂(H₂O)₄}Mo₆Se ₈(CN)₆] • 7H₂O (3) have been synthesized by layering of a methanol solution of [Mn(salen)]CH₃COO (salen-N,N′-bis(salicylidene)ethylenediamine) on an aqueous solution of K₇[Mo₆Se₈(CN)₆] • 8H ₂O. The compounds have been characterized by single-crystal X-ray diffraction analysis. All structures are based on negatively charged porous polymer frameworks where CN groups of [Mo₆Se₈(CN) ₆]^7- cluster complexes are coordinated to Mn²⁺ cations. Cavities in the frameworks are filled by additional cations and solvate water molecules.

Original language	English
Pages (from-to)	165-176
Number of pages	12
Journal	Journal of Cluster Science
Volume	20
Issue number	1
DOIs	https://doi.org/10.1007/s10876-008-0215-4
State	Published - Mar 2009

Bibliographical note

Funding Information:
Acknowledgements This research was supported by the SRC program of the Korea Science and Engineering Foundation (KOSEF) (Grant : R11-2005-008-03001-0). N. G. Naumov gratefully thanks KOSEF Brain Pool for financial support. Also we thank Prof. Vladislav A. Blatov (Samara State University) for the opportunity to use TOPOS4.0 Professional software package.

Keywords

Cluster Compounds
Crystal structure
Cyanides
Molybdenum

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10.1007/s10876-008-0215-4

Cite this

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title = "Novel three-dimensional coordination polymers based on [Mo 6Se8(CN)6]7- anions and Mn 2+ Cations",

abstract = "Three novel coordination polymers K5[MnMo6Se 8(CN)6] • 8H2O (1), (Me4N) 4[{Mn(H2O)2}1.5Mo6Se 8(CN)6] • 4H2O (2), and K 3[{Mn2(H2O)4}Mo6Se 8(CN)6] • 7H2O (3) have been synthesized by layering of a methanol solution of [Mn(salen)]CH3COO (salen-N,N′-bis(salicylidene)ethylenediamine) on an aqueous solution of K7[Mo6Se8(CN)6] • 8H 2O. The compounds have been characterized by single-crystal X-ray diffraction analysis. All structures are based on negatively charged porous polymer frameworks where CN groups of [Mo6Se8(CN) 6]7- cluster complexes are coordinated to Mn2+ cations. Cavities in the frameworks are filled by additional cations and solvate water molecules.",

keywords = "Cluster Compounds, Crystal structure, Cyanides, Molybdenum",

author = "Brylev, {Konstantin A.} and Naumov, {Nikolay G.} and Virovets, {Alexander V.} and Kim, {Sung Jin} and Fedorov, {Vladimir E.}",

note = "Funding Information: Acknowledgements This research was supported by the SRC program of the Korea Science and Engineering Foundation (KOSEF) (Grant : R11-2005-008-03001-0). N. G. Naumov gratefully thanks KOSEF Brain Pool for financial support. Also we thank Prof. Vladislav A. Blatov (Samara State University) for the opportunity to use TOPOS4.0 Professional software package.",

year = "2009",

month = mar,

doi = "10.1007/s10876-008-0215-4",

language = "English",

volume = "20",

pages = "165--176",

journal = "Journal of Cluster Science",

issn = "1040-7278",

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T1 - Novel three-dimensional coordination polymers based on [Mo 6Se8(CN)6]7- anions and Mn 2+ Cations

AU - Brylev, Konstantin A.

AU - Naumov, Nikolay G.

AU - Virovets, Alexander V.

AU - Kim, Sung Jin

AU - Fedorov, Vladimir E.

N1 - Funding Information: Acknowledgements This research was supported by the SRC program of the Korea Science and Engineering Foundation (KOSEF) (Grant : R11-2005-008-03001-0). N. G. Naumov gratefully thanks KOSEF Brain Pool for financial support. Also we thank Prof. Vladislav A. Blatov (Samara State University) for the opportunity to use TOPOS4.0 Professional software package.

PY - 2009/3

Y1 - 2009/3

N2 - Three novel coordination polymers K5[MnMo6Se 8(CN)6] • 8H2O (1), (Me4N) 4[{Mn(H2O)2}1.5Mo6Se 8(CN)6] • 4H2O (2), and K 3[{Mn2(H2O)4}Mo6Se 8(CN)6] • 7H2O (3) have been synthesized by layering of a methanol solution of [Mn(salen)]CH3COO (salen-N,N′-bis(salicylidene)ethylenediamine) on an aqueous solution of K7[Mo6Se8(CN)6] • 8H 2O. The compounds have been characterized by single-crystal X-ray diffraction analysis. All structures are based on negatively charged porous polymer frameworks where CN groups of [Mo6Se8(CN) 6]7- cluster complexes are coordinated to Mn2+ cations. Cavities in the frameworks are filled by additional cations and solvate water molecules.

AB - Three novel coordination polymers K5[MnMo6Se 8(CN)6] • 8H2O (1), (Me4N) 4[{Mn(H2O)2}1.5Mo6Se 8(CN)6] • 4H2O (2), and K 3[{Mn2(H2O)4}Mo6Se 8(CN)6] • 7H2O (3) have been synthesized by layering of a methanol solution of [Mn(salen)]CH3COO (salen-N,N′-bis(salicylidene)ethylenediamine) on an aqueous solution of K7[Mo6Se8(CN)6] • 8H 2O. The compounds have been characterized by single-crystal X-ray diffraction analysis. All structures are based on negatively charged porous polymer frameworks where CN groups of [Mo6Se8(CN) 6]7- cluster complexes are coordinated to Mn2+ cations. Cavities in the frameworks are filled by additional cations and solvate water molecules.

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