Novel infinite hexanuclear zinc coordination polymer with a flexible bipyridyl ligand and its catalytic activity

Yong Lee Jun; Jin Hong Sung; Cheal Kim; Sung Jin Kim; Youngmee Kim

doi:10.1016/j.inoche.2005.05.001

Novel infinite hexanuclear zinc coordination polymer with a flexible bipyridyl ligand and its catalytic activity

Yong Lee Jun, Jin Hong Sung, Cheal Kim, Sung Jin Kim, Youngmee Kim

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

The reaction of Zn(OTf)₂ with 1,3-bis(4-pyridyl)propane results in a novel infinite hexanuclear coordination polymer, [Zn₆(OH) ₈{(NC₅H₄)₂C₃H ₆}₄](OTf)₄ · 3H₂O, which was found to carry out the catalytic transesterification of esters with methanol at room temperature under the mild homogeneous conditions.

Original language	English
Pages (from-to)	692-696
Number of pages	5
Journal	Inorganic Chemistry Communications
Volume	8
Issue number	8
DOIs	https://doi.org/10.1016/j.inoche.2005.05.001
State	Published - Aug 2005

Bibliographical note

Funding Information:
This work was supported by the Korean Research Foundation (2002-070-C00053).

Keywords

Bipyridyl ligand
Crystal structure
Transesterification
Zn(II) coordination polymer

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10.1016/j.inoche.2005.05.001

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title = "Novel infinite hexanuclear zinc coordination polymer with a flexible bipyridyl ligand and its catalytic activity",

abstract = "The reaction of Zn(OTf)2 with 1,3-bis(4-pyridyl)propane results in a novel infinite hexanuclear coordination polymer, [Zn6(OH) 8{(NC5H4)2C3H 6}4](OTf)4 · 3H2O, which was found to carry out the catalytic transesterification of esters with methanol at room temperature under the mild homogeneous conditions.",

keywords = "Bipyridyl ligand, Crystal structure, Transesterification, Zn(II) coordination polymer",

author = "Jun, {Yong Lee} and Sung, {Jin Hong} and Cheal Kim and Kim, {Sung Jin} and Youngmee Kim",

note = "Funding Information: This work was supported by the Korean Research Foundation (2002-070-C00053). ",

year = "2005",

month = aug,

doi = "10.1016/j.inoche.2005.05.001",

language = "English",

volume = "8",

pages = "692--696",

journal = "Inorganic Chemistry Communications",

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T1 - Novel infinite hexanuclear zinc coordination polymer with a flexible bipyridyl ligand and its catalytic activity

AU - Jun, Yong Lee

AU - Sung, Jin Hong

AU - Kim, Cheal

AU - Kim, Sung Jin

AU - Kim, Youngmee

N1 - Funding Information: This work was supported by the Korean Research Foundation (2002-070-C00053).

PY - 2005/8

Y1 - 2005/8

N2 - The reaction of Zn(OTf)2 with 1,3-bis(4-pyridyl)propane results in a novel infinite hexanuclear coordination polymer, [Zn6(OH) 8{(NC5H4)2C3H 6}4](OTf)4 · 3H2O, which was found to carry out the catalytic transesterification of esters with methanol at room temperature under the mild homogeneous conditions.

AB - The reaction of Zn(OTf)2 with 1,3-bis(4-pyridyl)propane results in a novel infinite hexanuclear coordination polymer, [Zn6(OH) 8{(NC5H4)2C3H 6}4](OTf)4 · 3H2O, which was found to carry out the catalytic transesterification of esters with methanol at room temperature under the mild homogeneous conditions.

KW - Bipyridyl ligand

KW - Crystal structure

KW - Transesterification

KW - Zn(II) coordination polymer

UR - http://www.scopus.com/inward/record.url?scp=22044453980&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2005.05.001

DO - 10.1016/j.inoche.2005.05.001

M3 - Article

AN - SCOPUS:22044453980

SN - 1387-7003

VL - 8

SP - 692

EP - 696

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 8

ER -

Novel infinite hexanuclear zinc coordination polymer with a flexible bipyridyl ligand and its catalytic activity

Abstract

Bibliographical note

Keywords

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