Non-Toxic Natural Additives to Improve the Electrical Conductivity and Viscosity of Polycaprolactone for Melt Electrospinning

Jee Woo Kim; Seongho Park; Kyungsoon Park; Byung Kwon Kim

doi:10.3390/app13031844

Non-Toxic Natural Additives to Improve the Electrical Conductivity and Viscosity of Polycaprolactone for Melt Electrospinning

Jee Woo Kim, Seongho Park, Kyungsoon Park, Byung Kwon Kim

Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Polycaprolactone (PCL) is biodegradable and non-toxic, making it an eco-friendly polymer with various medical applications. In order to increase the stability of PCL used in the field of medical applications, it is necessary to be able to produce fibers with a melt electrospinning method that does not use toxic hydrophobic solvents. However, PCL has very high viscosity and low conductivity, making melt electrospinning difficult. This study presents natural additives enabling the solvent-free melt electrospinning of PCL, wherein the physical properties (i.e., conductivity and viscosity) of the additive-mixed PCL are analyzed. Among the natural additives added to PCL, 7 wt% gallic acid increased conductivity by 81 times and decreased viscosity by 1/8526 times, showing the best results. We believe that our study, improving the physical properties of melt PCL by adding natural additives, will be of great help to the development of the melt electrospinning method of PCL.

Original language	English
Article number	1844
Journal	Applied Sciences (Switzerland)
Volume	13
Issue number	3
DOIs	https://doi.org/10.3390/app13031844
State	Published - Feb 2023

Bibliographical note

Funding Information:
This work was supported by Korea Evaluation Institute Of Industrial Technology (KEIT) grant funded by the Ministry of Trade, Industry and Energy (MOTIE) (20017630, Materials/Parts Technology Development Program). B.K. was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF), funded by the Ministry of Education (2021R1A6A1A10039823), and the National Research Foundation (NRF) of Korea, funded by the Ministry of Science and ICT (NRF-2021R1A2C4002069). KS.P. acknowledges support from the Basic Science Research Program of the Research Institute for Basic Sciences (RIBS) of Jeju National University through the National Research Foundation of Korea (NRF), funded by the Ministry of Education (2019R1A6A1A10072987). This research was also supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF), funded by the Ministry of Education (NRF-2022R1I1A3072996).

Publisher Copyright:
© 2023 by the authors.

Keywords

electric conductivity
melt electrospinning
natural additives
polycaprolactone
viscosity

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10.3390/app13031844

Cite this

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title = "Non-Toxic Natural Additives to Improve the Electrical Conductivity and Viscosity of Polycaprolactone for Melt Electrospinning",

abstract = "Polycaprolactone (PCL) is biodegradable and non-toxic, making it an eco-friendly polymer with various medical applications. In order to increase the stability of PCL used in the field of medical applications, it is necessary to be able to produce fibers with a melt electrospinning method that does not use toxic hydrophobic solvents. However, PCL has very high viscosity and low conductivity, making melt electrospinning difficult. This study presents natural additives enabling the solvent-free melt electrospinning of PCL, wherein the physical properties (i.e., conductivity and viscosity) of the additive-mixed PCL are analyzed. Among the natural additives added to PCL, 7 wt% gallic acid increased conductivity by 81 times and decreased viscosity by 1/8526 times, showing the best results. We believe that our study, improving the physical properties of melt PCL by adding natural additives, will be of great help to the development of the melt electrospinning method of PCL.",

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author = "Kim, {Jee Woo} and Seongho Park and Kyungsoon Park and Kim, {Byung Kwon}",

note = "Funding Information: This work was supported by Korea Evaluation Institute Of Industrial Technology (KEIT) grant funded by the Ministry of Trade, Industry and Energy (MOTIE) (20017630, Materials/Parts Technology Development Program). B.K. was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF), funded by the Ministry of Education (2021R1A6A1A10039823), and the National Research Foundation (NRF) of Korea, funded by the Ministry of Science and ICT (NRF-2021R1A2C4002069). KS.P. acknowledges support from the Basic Science Research Program of the Research Institute for Basic Sciences (RIBS) of Jeju National University through the National Research Foundation of Korea (NRF), funded by the Ministry of Education (2019R1A6A1A10072987). This research was also supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF), funded by the Ministry of Education (NRF-2022R1I1A3072996). Publisher Copyright: {\textcopyright} 2023 by the authors.",

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N1 - Funding Information: This work was supported by Korea Evaluation Institute Of Industrial Technology (KEIT) grant funded by the Ministry of Trade, Industry and Energy (MOTIE) (20017630, Materials/Parts Technology Development Program). B.K. was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF), funded by the Ministry of Education (2021R1A6A1A10039823), and the National Research Foundation (NRF) of Korea, funded by the Ministry of Science and ICT (NRF-2021R1A2C4002069). KS.P. acknowledges support from the Basic Science Research Program of the Research Institute for Basic Sciences (RIBS) of Jeju National University through the National Research Foundation of Korea (NRF), funded by the Ministry of Education (2019R1A6A1A10072987). This research was also supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF), funded by the Ministry of Education (NRF-2022R1I1A3072996). Publisher Copyright: © 2023 by the authors.

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N2 - Polycaprolactone (PCL) is biodegradable and non-toxic, making it an eco-friendly polymer with various medical applications. In order to increase the stability of PCL used in the field of medical applications, it is necessary to be able to produce fibers with a melt electrospinning method that does not use toxic hydrophobic solvents. However, PCL has very high viscosity and low conductivity, making melt electrospinning difficult. This study presents natural additives enabling the solvent-free melt electrospinning of PCL, wherein the physical properties (i.e., conductivity and viscosity) of the additive-mixed PCL are analyzed. Among the natural additives added to PCL, 7 wt% gallic acid increased conductivity by 81 times and decreased viscosity by 1/8526 times, showing the best results. We believe that our study, improving the physical properties of melt PCL by adding natural additives, will be of great help to the development of the melt electrospinning method of PCL.

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Non-Toxic Natural Additives to Improve the Electrical Conductivity and Viscosity of Polycaprolactone for Melt Electrospinning

Abstract

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Keywords

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