Nitroxyl radicals: Electrochemical redox behaviour and structure-activity relationships

Sushma Manda, Ikuo Nakanishi, Kei Ohkubo, Haruko Yakumaru, Ken Ichiro Matsumoto, Toshihiko Ozawa, Nobuo Ikota, Shunichi Fukuzumi, Kazunori Anzai

Research output: Contribution to journalArticlepeer-review

38 Scopus citations

Abstract

Comparative study of electrochemical redox behaviour of five different nitroxyl radicals leads to the direct correlation between one-electron redox potentials and group electronegativity of the β-substituent on the ring. β-Substituents with an electron-donating effect caused a negative shift in the one-electron oxidation and one-electron reduction potentials of the nitroxyl radicals. In a similar aspect, β-substituents with an electron-withdrawing effect behaved oppositely.

Original languageEnglish
Pages (from-to)3951-3955
Number of pages5
JournalOrganic and Biomolecular Chemistry
Volume5
Issue number24
DOIs
StatePublished - 2007

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