New trans-[Re6S8(CN)4L2] n- rhenium cluster complexes: Syntheses, crystal structures and properties

Nikolay G. Naumov; Alexandra Y. Ledneva; Sung Jin Kim; Vladimir E. Fedorov

doi:10.1007/s10876-009-0233-x

New trans-[Re₆S₈(CN)₄L₂] ^n- rhenium cluster complexes: Syntheses, crystal structures and properties

Nikolay G. Naumov, Alexandra Y. Ledneva, Sung Jin Kim, Vladimir E. Fedorov

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

Reaction of polymeric compound Cs₄[Re₆S ₈(CN)₄S_2/2] with aqueous solution of KOH led to formation of trans-[Re₆S₈(CN)₄(OH) ₂]^4- anion which was crystallized in ordered Cs _1.68K_2.32[Re₆S₈(CN) ₄(OH)₂] • 2H₂O (1a) and disordered Cs _1.83K_2.17[Re₆S₈(CN) ₄(OH)₂] • 2H₂O (1b) modifications. The presence of two types of apical ligands, inert cyanides and labile hydroxides, opened a way to other trans-[Re₆S₈(CN)₄L ₂] ^n- rhenium cluster complexes: trans-[Re ₆S₈(CN)₄Cl₂]^4-, trans-[Re₆S₈(CN)₄(H₂O)Br] ^3-, and trans-[Re₆S₈(CN)₄Br ₂]^4-, crystallized as Cs_1.84K _1.16(H)[Re₆S₈(CN)₄Cl₂] (2), Cs_1.68K_1.32[Re₆S₈(CN) ₄(H₂O)Br] (3), (Me₄N)₃(H ₅O₂)[Re₆S₈(CN)₄Br ₂] (4), and CsK{Cu(H₂O)₂[Re₆S ₈(CN)₄Cl₂]} • 4H₂O (5) salts.

Original language	English
Pages (from-to)	225-239
Number of pages	15
Journal	Journal of Cluster Science
Volume	20
Issue number	1
DOIs	https://doi.org/10.1007/s10876-009-0233-x
State	Published - Mar 2009

Keywords

Cluster compounds
Crystal structure
Cyanides
Rhenium

Access to Document

10.1007/s10876-009-0233-x

Cite this

@article{a33c29df0b804736b0a42d46c29d68fb,

title = "New trans-[Re6S8(CN)4L2] n- rhenium cluster complexes: Syntheses, crystal structures and properties",

abstract = "Reaction of polymeric compound Cs4[Re6S 8(CN)4S2/2] with aqueous solution of KOH led to formation of trans-[Re6S8(CN)4(OH) 2]4- anion which was crystallized in ordered Cs 1.68K2.32[Re6S8(CN) 4(OH)2] • 2H2O (1a) and disordered Cs 1.83K2.17[Re6S8(CN) 4(OH)2] • 2H2O (1b) modifications. The presence of two types of apical ligands, inert cyanides and labile hydroxides, opened a way to other trans-[Re6S8(CN)4L 2] n- rhenium cluster complexes: trans-[Re 6S8(CN)4Cl2]4-, trans-[Re6S8(CN)4(H2O)Br] 3-, and trans-[Re6S8(CN)4Br 2]4-, crystallized as Cs1.84K 1.16(H)[Re6S8(CN)4Cl2] (2), Cs1.68K1.32[Re6S8(CN) 4(H2O)Br] (3), (Me4N)3(H 5O2)[Re6S8(CN)4Br 2] (4), and CsK{Cu(H2O)2[Re6S 8(CN)4Cl2]} • 4H2O (5) salts.",

keywords = "Cluster compounds, Crystal structure, Cyanides, Rhenium",

author = "Naumov, {Nikolay G.} and Ledneva, {Alexandra Y.} and Kim, {Sung Jin} and Fedorov, {Vladimir E.}",

year = "2009",

month = mar,

doi = "10.1007/s10876-009-0233-x",

language = "English",

volume = "20",

pages = "225--239",

journal = "Journal of Cluster Science",

issn = "1040-7278",

publisher = "Springer New York",

number = "1",

}

TY - JOUR

T1 - New trans-[Re6S8(CN)4L2] n- rhenium cluster complexes

T2 - Syntheses, crystal structures and properties

AU - Naumov, Nikolay G.

AU - Ledneva, Alexandra Y.

AU - Kim, Sung Jin

AU - Fedorov, Vladimir E.

PY - 2009/3

Y1 - 2009/3

N2 - Reaction of polymeric compound Cs4[Re6S 8(CN)4S2/2] with aqueous solution of KOH led to formation of trans-[Re6S8(CN)4(OH) 2]4- anion which was crystallized in ordered Cs 1.68K2.32[Re6S8(CN) 4(OH)2] • 2H2O (1a) and disordered Cs 1.83K2.17[Re6S8(CN) 4(OH)2] • 2H2O (1b) modifications. The presence of two types of apical ligands, inert cyanides and labile hydroxides, opened a way to other trans-[Re6S8(CN)4L 2] n- rhenium cluster complexes: trans-[Re 6S8(CN)4Cl2]4-, trans-[Re6S8(CN)4(H2O)Br] 3-, and trans-[Re6S8(CN)4Br 2]4-, crystallized as Cs1.84K 1.16(H)[Re6S8(CN)4Cl2] (2), Cs1.68K1.32[Re6S8(CN) 4(H2O)Br] (3), (Me4N)3(H 5O2)[Re6S8(CN)4Br 2] (4), and CsK{Cu(H2O)2[Re6S 8(CN)4Cl2]} • 4H2O (5) salts.

AB - Reaction of polymeric compound Cs4[Re6S 8(CN)4S2/2] with aqueous solution of KOH led to formation of trans-[Re6S8(CN)4(OH) 2]4- anion which was crystallized in ordered Cs 1.68K2.32[Re6S8(CN) 4(OH)2] • 2H2O (1a) and disordered Cs 1.83K2.17[Re6S8(CN) 4(OH)2] • 2H2O (1b) modifications. The presence of two types of apical ligands, inert cyanides and labile hydroxides, opened a way to other trans-[Re6S8(CN)4L 2] n- rhenium cluster complexes: trans-[Re 6S8(CN)4Cl2]4-, trans-[Re6S8(CN)4(H2O)Br] 3-, and trans-[Re6S8(CN)4Br 2]4-, crystallized as Cs1.84K 1.16(H)[Re6S8(CN)4Cl2] (2), Cs1.68K1.32[Re6S8(CN) 4(H2O)Br] (3), (Me4N)3(H 5O2)[Re6S8(CN)4Br 2] (4), and CsK{Cu(H2O)2[Re6S 8(CN)4Cl2]} • 4H2O (5) salts.

KW - Cluster compounds

KW - Crystal structure

KW - Cyanides

KW - Rhenium

UR - http://www.scopus.com/inward/record.url?scp=67349217476&partnerID=8YFLogxK

U2 - 10.1007/s10876-009-0233-x

DO - 10.1007/s10876-009-0233-x

M3 - Article

AN - SCOPUS:67349217476

SN - 1040-7278

VL - 20

SP - 225

EP - 239

JO - Journal of Cluster Science

JF - Journal of Cluster Science

IS - 1