New fluorescent chemosensors for silver ion

Jongmin Kang, Miwhoa Choi, Ji Young Kwon, Eun Yeol Lee, Juyoung Yoon

Research output: Contribution to journalArticlepeer-review

93 Scopus citations

Abstract

New fluorescent chemosensors, 1,8-bis(pyrazolyl-methyl)anthracene and 9,10-bis(pyrazolylmethyl)anthracene, were synthesized. The 1,8-isomer showed selective fluorescent quenching effects with Ag(I) and Cu(II). On the other hand, the 9,10-isomer displayed a selective fluorescent quenching effect only with Ag(I). From the association constants obtained from fluorescent titrations and by extraction, we conclude that rigid immobilization of the ligands, 1,8-isomer, plays a more important role in the binding with Ag(I) than the additional -cation interaction offered by the 9,10-isomer.

Original languageEnglish
Pages (from-to)4384-4386
Number of pages3
JournalJournal of Organic Chemistry
Volume67
Issue number12
DOIs
StatePublished - 14 Jun 2002

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